ISSN:
1572-879X
Schlagwort(e):
Carbon deposition
;
hydrogen effect
;
nickel
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract The role of hydrogen in carbon deposition on Ni has been studied at H2/CO 〈 1 and 698 K by determining the respective rates of the carbon-forming reactions: (1) CO + H2 →-C + H2O and (2) 2CO → C + CO2. The steady-state rate of reaction (1) increases in proportion to H2 pressure. On the other hand, reaction (2) is facilitated by the addition of an extremely small amount of H2, so that the rate becomes about eight times that for pure CO but hardly varies as more H2 is added. Similarly, there is a great difference in catalytic activity for ethylene hydrogenation between spent catalysts obtained in the deposition with and without H2. These findings suggest that hydrogen, even in a small amount, makes free Ni surface area larger than for pure CO.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00811358
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