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  • 1985-1989  (2)
  • Chemical Engineering  (1)
  • Prototropic equilibria  (1)
Materialart
Erscheinungszeitraum
  • 1985-1989  (2)
Jahr
Schlagwörter
  • 1
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 473-482 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Rates of mass and momentum transport in narrow flow channels (gaps 0.2-0.5 mm) have been determined over a wide range of flow velocities, 220-7,700 cm/sec (Re 1,300 to 22,000). Existing correlations that apply to smooth channels of much larger hydraulic diameter were found to be valid for the narrow channels as well. However, in the turbulent regime the condition of hydraulic smoothness could be satisfied only when the walls were optically smooth. Transport rates to rough walls were also measured. The ratio of the mass transport to the momentum transport in the form of jD/(f/2) - a measure of the improved mass transfer compared to the increased pressure drop - is given for the smooth and rough-wall cells over the Re range studied.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 25 (1987), S. 16-20 
    ISSN: 0749-1581
    Schlagwort(e): 13C NMR ; 13C Relaxation Times ; Prototropic equilibria ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Quaternary 13C dipole-dipole spin-lattice relaxation times are used to analyse prototropic equilibria of 2-acetylbenzimidazole (1) and 4-azabenzimidazole in DMSO-d6 solutions. For the first compound, fast exchange between the two chelated structures prevails for 13C relaxation times, whereas proton and 13C chemical shifts characterize a slow exchange. For 4-azabenzimidazole, 13C and 1H spectra do not exhibit absorptions from structures in slow exchange. Analysis of the T1 values of carbons 8 and 9 before and after isotopic exchange of the labile amino hydrogen clearly show that the major component of the equilibrium is the 3H structure.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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