Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • General Chemistry  (254)
  • Polymer and Materials Science  (161)
  • Chemical Engineering  (17)
  • 1
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 54 (1941), S. 213-215 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Modification of fluorine-containing polymers has recently received much attention due to new chemistries allowing for refunctionalization of these materials, especially their surfaces. In this article results are discussed which demonstrate various interesting modifications (including incorporations of —OH and oxygen comprised functionality) to expanded poly(tetrafluoroethylene) (ePTFE) surfaces. This is effected through the use of low damage, radio frequency glow discharge (RFGD) processes. The low damage conditions, which preserve the original pore structure/morphology of these RFGD treated materials, are supported by Scanning Electron Microscopy (SEM) while the resulting atomic and molecular effects are investigated through other surface analytical methodology. All materials reported in this investigation have been subjected to intensive structural analyses utilizing Electron Spectroscopy for Chemical Analysis (ESCA), Attenuated Total Reflectance Fourier Transform Infrared spectroscopy (ATR-FTIR), and wettability profiles obtained through contact angle measurements using a large series of liquids having varying surface tensions and surface reactive functionality. Through this multitechnique analysis of both expanded PTFE and poly(vinylidene fluoride) (PVDF) treated surfaces, a model is supported which illustrates surfaces possessing both high and low energy regions comprising both oxygen and fluorine functionality in close molecular proximity.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Recent work in our laboratories has fully characterized the surface region of a segmented poly(ether-urethane) (PEU) extending from the air/polymer interfacial region through bulk depths in the micron range. This characterization utilized energy and angle dependent Electron Spectroscopy for Chemical Analysis (ESCA), Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR), and Comprehensive Wettability Profiling (contact angle using a homologous series of liquids) as defined by Zisman. In this study this same multi-analytical-technique approach is used to elucidate changes in these PEU surfaces induced through an H2O Radio Frequency Glow Discharge (RFGD) plasma. This investigation reports both qualitative and quantitative changes due to the modification treatments as well as the permanency of the changes effected on these surfaces through the plasma treatment. From our analyses, the amount of surface residing polyurethane (hard segment) is observed to increase due to a proposed plasma etching mechanism. Further, the addition of oxygen containing functionality is detected at the modified surfaces unique with respect to the unmodified PEU. These surface modifications which show large increases in wettability, are finally observed to be semi-permanent over a time period of 6 months.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2141-2149 
    ISSN: 0887-624X
    Keywords: polyimides ; 4-phenylethynylphthalic anhydride ; thermooxidative stability ; high-temprature MAS NMR ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of high glass transition temperature (Tg 〉 300°C), amorphous, soluble, poly-imide oligomers of controlled molecular weight endcapped with 4-phenylethynylphthalic anhydride endcapping agent is described. The 4-phenylethynylphthalic anhydride was employed to afford a higher curing temperature (380-420°C) which widens the processing window compared to unsubstituted acetylene-endcapped polyimides. The polyimides were synthesized via solution imidization techniques, using the ester-acid of various dianhydrides and aromatic diamines. A “ one-pot” procedure utilizing NMP as the solvent and o-dichlo-robenzene as the azeotroping agent reproducibly produced fully imidized, but yet soluble wholly aromatic polyimides. Thermally cured samples were prepared with gel contents of up to 98% that displayed good solvent resistance. Glass transition temperatures comparable to high molecular weight linear analogs were produced. These polyimides also show excellent thermal stability as judged by thermogravimetric analysis (TGA). Model phenylethynyl imide compounds were synthesized and used to follow and elucidate the nature of the products formed from the phenylethynyl curing by using high temperature magic-angle 13C nuclear magnetic resonance (MAS NMR). Preliminary results indicate that the cure reaction can be followed by MAS NMR. However, the nature of the products being formed during the curing process is difficult to determine by the solid-state MAS NMR alone. Differential scanning calorimetry (DSC) data clearly show that the model system does indeed melt and displays a wide window before the strong cure exotherm is observed. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 10 (1979), S. 449-455 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Prevention of Inertial Force Measurement Inaccuracies Encountered in Pendulum-type DynamometersTest machines, which are equipped with a force measuring device utilizing the inclining pendulum, are subject to dynamic measurement inaccuracies due to the inertia of the pendulum.The initial discussion demonstrates that the dynamic inaccuracy of measurement encountered with test machines using an inclining pendulum - force measurement device can only be calculated for the complete test machine/test piece configuration. With reference to the results of experiments, it will be proved that, as with the experiments carried out by Kravcenko, the indicated dynamic force and the dynamic force in the testpiece are antiphase and unequal.Additionally it will be shown that, through the experiment results, the equation from Schultze/Baumann for the permissible rate of test is confirmed only in the interpretation from Kravcenko.Further equations concerning the limitations of the rate of test are shown and their relevant fields of applications are discussed. Finally, factors are presented which stipulate a reduction of the permissible rate of test or permit an increase in this rate, dependent upon the force-elongation characteristic of the test piece and the measured variable under consideration.
    Notes: An Prüfmaschinen, welche Kraftmeßeinrichtungen mit Neigungspendeln besitzen, treten durch die Trägheit des Pendels dynamische Meßfehler auf.Es wird zunächst klargestellt, daß die dynamischen Meßfehler bei Prüfmaschinen mit Neigungspendel-Kraftmeßeinrichtungen nur für das Gesamtsystem Prüfmaschine/Probe berechnet werden können.Anhand von Versuchsergebnissen wird nachgewiesen, daß - entsprechend Untersuchungen von Kravčko - die angezeigte dynamische Kraft und die dynamische Probenkraft gegenphasig und ungleich sind. Außerdem wird gezeigt, daß durch die Versuchsergebnisse die Gleichg. von Schultze/Baumann für die zulässige Prüfgeschwindigkeit nur in der Deutung von Kravčko bestätigt wird.Weitere Gleichungen für Die Begrenzung der Prüfgeschwindigkeit wer den angegeben und ihr Einsatzbereich besprochen. Schließlich werden Faktoren angegeben, die je nach dem Kraft-Verlängerungs-Verhalten der Probe und je nach der gesuchten Meßgröße eine Verringerung der zulässigen Prüfgeschwindigkeit bedingen oder eine Vergrößerung der selben zulassen.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 14 (1983), S. 45-57 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Stabiles Rißwachstum-Charakterisierung des Verhaltens nicht-wanddurchdringender RisseDas Verhalten von nicht-wanddurchdringenden Fehlern, die durch halb-elliptische Oberflächenfehler dargestellt werden, unter beliebiger Normalspannungsverteilung (linearisiert) wird untersucht. Einflüsse des Fehlerwachstumsgesetzes, der Fehlerlage, der Geometrie und der Spannungsumlagerungen zusammen mit Plastizitätseffekten werden diskutiert. Die relative Endfehlerlänge für den Wanddurchbruch wird bestimmt. Die Ergebnisse werden erörtert im Zusammenhang mit den Bedingungen für Leck-vor-Bruch, promptes-Versagen und kein-Leck-vor-Bruch/kein-promptes Versagen.
    Notes: The behaviour of part-through cracks, modelled by semi-elliptical surface cracks, under variable normal stresses (linearized) is investigated. The stable crack contour, given as crack aspect ratio, is determined for an infinite body as a circle; in a finite body semi-ellipses are “quasi”- stable. The effects of crack growth law types, crack location, geometry and stress redistribution together with plasticity effects are discussed. The final relative crack lengths for wall penetration are determined. The data are discussed with respect to the conditions for leak-before-break, sudden rupture and no-leak-before-break/no-sudden-rupture.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 11 (1960), S. 601-616 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Flame spraying of aluminaCeramic coatings produced by the flame spraying process are intended to protect the basic material against corrosion, erosion and oxidation as well as to act as a thermal barrier. For this purpose, alumina was found to be particularly well suited because of its high melting point, hardness, chemical resistance and other favourable properties. With this material as a model substance, the basic processes encountered with the spraying of ceramic powders have been investigated. The investigations comprised the melting process in the flame jet, the composition, lattice structure and physical properties of the spray coating, and the adhesion of the latter on pure metals and alloys with different surface roughness conditions.Although the porosity of these coatings is small, it prevents them from offering complete protection against corrosion and oxidation. But the protection effect can be enhanced by using resistant intermediate metal or enamel layers, and by stabilizing the sprayed coating. Owing to their high abrasion resistance and thermal barrier effect, these coatings have already found a wide field of application.
    Notes: Nach dem Flammspritzverfahren hergestellte keramische Überzüge haben die Aufgabe, das Grundmaterial gegen Korrosion, Erosion and Oxydation zu schützen sowie als Wärmeschranke zu wirken. Besonders geeignet erweist sich hierfür Aluminiumoxyd wegen seines hohen Schmelzpunktes, seiner Härte, seiner chemischen Resistenz und anderer günstiger Eigenschaften. Mit diesem Material als Modellsubstanz wurden die grundlegenden Vorgänge beim Spritzen von Keramik-Pulvern verfolgt. Die Untersuchungen erstreckten sich auf den Schmelzvorgang im Flammstrahl, auf den Aufbau, die Gitterstruktur und die physikalischen Eigenschaften der Spritzschicht sowie auf deren Haftung auf Reinmetallen und Legierungen mit verschiedener Oberflächenaufrauhung.Die Überzüge bieten wegen ihrer, wenn auch geringen Porosität keinen vollständigen Schutz gegen Korrosion und Oxydation. Durch Verwendung von resistenten Zwischenschichten aus Metall oder Email und durch Stabilisierung der Spritzschicht kann die Schutzwirkung jedoch erhöht werden. Auf Grund ihrer Abriebfestigkeit und ihrer wärmedämmenden Wirkung haben die Überzüge bereits ein weites Anwendungsgebiet gefunden.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 51-58 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of large-diameter pipes made of hard polyethyleneWith the aid of numerous illustrations, the applications of polyethylene pipes of relatively large diameters are surveyed. A special account is given of the advantages which such pipes may offer under different installation conditions. Especially in the Scandinavian countries  -  Norway, Finland and Sweden  -  where pipes are laid in the open even during the winter months, the toughness of hard polyethylene, even at low temperatures, is found to be a particular advantage. A special problem is posed by the need for a reliable jointing of large-diameter pipes. It is shown that, if the necessary conditions are adhered to, and if suitable aids are used, it is possible to obtain reliable butt welds, both between one pipe and another, and between pipe and welding collar. Such welding collars can be made in different ways. For instance, a mould is filled with the aid of an extruder and a rough cast prepared which, after cooling, is machined on a lathe. Pipes made of hard polyethylene are used not only for drinking water pipes but also for special purposes, e. g. cable protection pipes. For this purpose, a special technique, known as jetting method, is sometimes used for laying pipes across water.
    Notes: Anhand einer großen Anzahl van Bildern wird über den Einsatz van Rohren relativ großen Durchmessers aus Hart-Polyäthylen berichtet. Dabei wird auch auf die Vorteile, die solche Rohre unter den verschiedensten Verlegebedingungen bieten, näher eingegangen. Gerade in skandinavischen Ländern wie Norwegen, Finnland und Schweden, wo auch während der Wintermonate Rohrverlegungen im Freien stattfinden, erweist sich die gute Zähigkeit von Hart-Polyäthylen auch in der Kälte von besonderem Vorteil. Ein besonderes Problem stellt die zuverlässige Verbindung von Rohren großen Durchmessers der. Es wird gezeigt, daß bei Einhaltung der erforderlichen Bedingungen und bei Verwendung geeigneter Hilfsgeräte einwandfreie Stumpfschweißungen sowohl der Rohre untereinander als auch von Rohr und Vorschweißbund erzielt werden können. Die Herstellung solcher Vorschweißbunde kann auf verschiedene Arten vorgenommen werden; z. B. wird mit Hilfe eines Extruders eine Form gefüllt und durch Pressen ein Rohling hergestellt, der nach dem Erkalten auf einer Drehbank bearbeitet wird. Neben der Verwendung van Rohren aus Hart-Polyäthylen für Trinkwasserleitungen werden sie auch für Spezialzwecke, wie z. B. Kabelschutzrohre, eingesetzt. Dabei wird in manchen Fällen eine besondere Verlegetechnik beim Durchqueren van Gewässern, das sog. Einspülverfahren, angewandt.
    Additional Material: 36 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 10
    ISSN: 1042-7147
    Keywords: interpenetrating polymer networks ; kinetics ; phase separation ; X-ray scattering ; light scattering ; polyurethane ; polystyrene ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Phase separation that takes place during the formation of semi-interpenetrating polymer networks based on crosslinked polyurethane and linear polystyrene was studied by small-angle X-ray scattering and light scattering. The kinetics of the chemical reactions was followed by Fourier transform infrared spectroscopy. The occurrence of broad peaks in the X-ray scattering curves was interpreted in terms of distances between the urethane crosslinks. Small modulations on these curves were assigned to sphere-like structures with a diameter of around 5 nm which might be related to the urethane crosslink regions. Small modulations on the light-scattering curves at the beginning of styrene polymerization were assigned to spheres with diameters of around 4.5 μm, which can be related to the polystyrene-rich phase. These modulations disappear with time, which might indicate an increasing polydispersity of the domain sizes. The final morphology was found to depend on the time at which polymerization of styrene is initiated with respect to the time of gelation of polyurethane.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...