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  • 1
    ISSN: 1432-1009
    Schlagwort(e): Sulfate ; Nitrate ; Critical loads ; Modeling ; Deposition standards
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The critical loads approach is emerging as an attractive means for evaluating the effects of atmospheric deposition on sensitive terrestrial and aquatic ecosystems. Various approaches are available for modeling ecosystem responses to deposition and for estimating critical load values. These approaches include empirical and statistical relationships, steady-state and simple process models, and integrated-effects models. For any given ecosystem, the most technically sophisticated approach will not necessarily be the most appropriate for all applications; identification of the most useful approach depends upon the degree of accuracy needed and upon data and computational requirements, biogeochemical processes being modeled, approaches used for representing model results on regional bases, and desired degree of spatial and temporal resolution. Different approaches are characterized by different levels of uncertainty. If the limitations of individual approaches are known, the user can determine whether an approach provides a reasonable basis for decision making. Several options, including point maps, grid maps, and ecoregional maps, are available for presenting model results in a regional context. These are discussed using hypothetical examples for choosing populations and damage limits.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 57 (1989), S. 1069-1098 
    ISSN: 1572-9613
    Schlagwort(e): Block copolymers ; generating function ; Polya's theorem ; gelation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We determine the statistical properties of block copolymer complexes in solution. These complexes are assumed to have the topological structure of (i) a tree or of (ii) a line-dressed tree. In case the structure is that of a tree, the system is shown to undergo a gelation transition at sufficiently high polymer concentration. However, if the structure is that of a line-dressed tree, this transition is absent. Hence, we show the assumption about the topological structure to be relevant for the statistical properties of the system. We determine the average size of the complexes and calculate the viscosity of the system under the assumption that the complexes geometrically can be treated as porous spheres.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 57 (1989), S. 1099-1122 
    ISSN: 1572-9613
    Schlagwort(e): Block copolymers ; generating function method ; Polya's theorem ; gelation ; nonnested structures
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We determine the statistical properties of block copolymers in solution. These complexes are assumed to have the topological structure of connected graphs with “nonnested” loops and cycles. The generating function method is used to determine the number of topologically different complexes containing a given number of block copolymers. It is shown that at sufficiently high concentration the system undergoes a transition to a gel phase. Furthermore, the average number of polymers per complex is calculated. Finally, the relative increase in viscosity is found under the assumption that the complexes can be treated as porous spheres.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 643-653 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Shear stress and first normal stress difference data are presented for several polymer solutions undergoing steady shear rates from 1.0 to 100,000 sec.-1. The steady shear response is divided into three regions as a function of increasing shear rate. These are the diffusion controlled linear region, a moderate shear rate region where shear controls the entanglement-disentanglement process, and a high shear rate region where aggregation of polymer molecules occurs. The transitions between the three regions are clearly illustrated by using a group designated as the rotation rate function.A molecular model is derived for the shear controlled region that allows prediction of the first normal stress difference from the viscosity function and one additional constant that depends only on the molecular species. The White-Metzner equation is found to adequately describe the aggregation region at high shear rates.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 682-688 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The stability of cylindrical jets in immiscible liquid systems is analyzed with the low velocity theory of Tomotika. For the first time the several limiting solutions in the literature are obtained from a general equation, so approximate restrictions on their applicability can be presented. These restrictions show that for many systems none of the limiting solutions is valid. Correlations applicable to all Newtonian liquid-liquid systems are presented for predicting the growth rate and wavelength of the most unstable disturbance.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 689-699 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The stability theory is used to predict jet length from jet inception to disruption for injection of one Newtonian liquid into a second immiscible Newtonian liquid. Knowledge of the length is essential for predicting the size of drops formed from jets. At low velocities jet length is controlled by the amplification of symmetrical waves which travel at the interfacial velocity of the jet. At higher velocities an abrupt lengthening of the jet may occur as a result of drop merging, and the jet length is then controlled by the growth rate of sinuous waves which are strongly velocity dependent. Jet disruption results from a geometrical limitation on the maximum amplitude of the sinuous waves. Predictions show good quantitative agreement with experimental data for thirteen mutually saturated systems over a wide range of variables and qualitative agreement with limited experimental data on the effects of initial disturbance level and mass transfer.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 9-15 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A correlation is presented for predicting the drop volume for injection at low velocities of one Newtonian liquid into a second stationary immiscible Newtonian liquid in the absence of surface active agents. The analysis, which is based on a two-stage process of drop formation, predicts drop volumes within an average error of 11% for fifteen liquid-liquid systems covering a wider range of variables than any previous study. Although the equation was tested primarily with mutually saturated liquids, if correctly predicted drop size for two systems where mass transfer was occurring.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 700-706 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A theoretical analysis is presented for predicting the size of drops formed from a laminar cylindrical jet when one Newtonian liquid is injected through a nozzle into a second immiscible Newtonian liquid. The analysis couples stability theory with the requirement that the disturbances travel at the same velocity as the jet interface. Comparison of the theory with experimental data for thirteen mutually saturated liquid-liquid systems covering a wide range of physical properties shows a mean error of 11.7% in prediction of the specific surface.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Plant/Operations Progress 5 (1986), S. 52-56 
    ISSN: 0278-4513
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An innovation which allows gas rates up to three times those allowable in conventional pads.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 10
    ISSN: 0736-0266
    Schlagwort(e): Sulfate ; Cartilage ; Glycosaminoglycans ; Mouse ; Articular ; Life and Medical Sciences
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin
    Notizen: We have studied the effect of environmental sulfate concentration on the glycosaminoglycan synthesis of anatomically intact patellar cartilage of the mouse in vitro. Incubation of mouse patellae in medium with sulfate concentrations below 0.5 mM resulted in a diminished incorporation of sulfate but in unaltered incorporation of glucosamine. This suggested the synthesis of undersulfated glycosaminoglycans under these conditions. We characterized glycosaminoglycans synthesized at three different sulfate concentrations: a sulfate concentration physiological for the mouse (1.0 mM), a sulfate concentration in the range where sulfate incorporation was strongly diminished (0.1 mM), and an extremely low sulfate concentration (10 nM). Analysis of glycosaminoglycan disaccharides and DEAE anion chromatography of the glycosaminoglycans could not confirm the synthesis of undersulfated glycosaminoglycans at 0.1 mM. The chromatogram of glycosaminoglycans synthesized in medium containing 10 nM showed the presence of a very low sulfated glycosaminoglycan pool not observed at higher medium sulfate concentrations. Intermediately sulfated glycosaminoglycans were also synthesized during incubation with 10 nM sulfate. So, our data indicate that only very low sulfate concentrations in the medium lead to the synthesis of undersulfated glycosaminoglycans and that the sulfation mechanism of murine patellar cartilage chondrocytes does not seem to fit completely in an “all-or-nothing” pattern.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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