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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 747-752 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The radial components of the turbulence energy and intensity spectra within a stirred, baffled tank are measured with a transducer probe of the type developed by Eagleson et al. (9). The spectra are normalized because absolute levels of the intensity in these high intensity velocity fields cannot be measured with the present technique. Average velocities are also measured with Pitot and Prandtl tubes.Range of measured energy and intensity spectra was 19 to 1,100 cycles/sec. The measured energy spectra show a k-5/3-relation in the low wave number range where the wave number k is less than 100 ft.-1 and a k-10/3-relation in the wave number range of 100 to 1,000 ft.-1. This behavior is found regardless of impeller size, motor speed, and position in tank, in particular radial distance, indicating that the decay of energy spectra is self-preserving. Increasing the viscosity from 0.80 to 103 centipoises results in a progressively steeper slope in the high wave number range. The shape of the intensity spectra is the same as that of the concentration spectra measured by Manning (26, 27).
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 2446-2455 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In cyclones, the boundary layer formed on the collecting-wall surface acts as a barrier for particle migration toward the wall due to a decreased centrifugal force on particles inside the boundary layer. A new theory for high-efficiency cyclones based on the boundary-layer characteristics is presented. The cyclone was divided into two regions: the turbulent-core region where the centrifugal force is large, and the near-wall region where the centrifugal force is small. Particle trajectories in the turbulent-core region are calculated from the mean fluid motion based on the quasi-steady drag assumption, and the collection probability of particles in the near-wall region is calculated by the deposition velocity that results from both turbulent diffusion and centrifugal force. The deposition velocity by centrifugal force was assumed equal to the equilibrium migration velocity at a certain point inside the boundary layer, and the distance to that point from the wall is assumed to be linearly proportional to the dimensionless-particle relaxation time. When the proportional constant was determined by fitting the theoretical results to experimental data, the theory showed an excellent enhancement in predicting the variation of collection efficiency with the inlet flow velocity and particle size.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 1115-1125 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of bisphenol-A polycarbonate (PC) with poly- (styrene-co-acrylonitrile) (SAN) and poly (acrylonitrile-butadiene-styrene) (ABS) prepared by screw extrusion and solution-casting were investigated by differential scanning calorimetry and scanning electron microscopy. From the measured glass-transition temperatures (Tg) and specific heat increments (ΔCp) at the Tg, SAN appears to dissolve more in the PC-rich phase than does PC in the SAN-rich phase. Also, the decrease of Tg (PC) in PC/ABS blends is larger than in the PC/SAN blends. From the Tg behavior and the electron microscopy study, it is suggested that the compatibility increases more in the SAN-rich compositions than in the PC-rich compositions of the blends. In the study of extrudate swell of the PC/SAN blends and the PC/ABS blends, the maximum level of extrudate swell is reached at 0.5 weight fraction of PC for both blend systems. The Flory-Huggins polymer-polymer interaction parameter (χ12) between PC and SAN was calculated and found to be 0.034 ± 0.004. A similar value of χ for PC and SAN was found with the PC/ABS blends.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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