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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 366-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The alternating flow model (AFM) views dispersion in packed beds as a sequence of streamline plugs that must repeatedly split and merge as the bulk fluid traverses the vessel. Thus, the flow in the AFM is ordered, as opposed to the random flow implied by the Fickian analogy. For mass dispersion only, model parameters arise from a priori considerations of packing geometry. Steady state and transient data (5.6 〈 Dt/dp 〈 54.4, 100 〈 Rep 〈 1,000, gases and liquids) show the AFM to surpass the Fickian analogy (based on correlations for dispersion coefficients) in most cases. Further, it can describe well the radial velocity profile trends in packed beds. For heat dispersion, two additional parameters (heat transfer coefficients) arise that are not functions of packing geometry. Simple correlations for these parameters and the justifications are given. Most of the comparisons made with the literature experimental results show the AFM to be at least as good as the back-fit Fickian analogy. The AFM should be most useful for packed beds with a relatively small Dt/dp.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 309-312 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 128-136 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new experimental method for the measurement of catalyst surface area of supported catalysts has been developed using selective physisorption. The desorption characteristics of a gas are studied separately on the catalyst, the support, and the supported catalyst by carrying out thermal desorption experiments in a continuous flow sorptometer. Differences in the coverage vs. temperature curves, obtained from the thermal desorption experiments, are a measure of the selectivity of the physisorbing gas, and allow calculation of the fraction of total surface area occupied by the catalyst.Two systems have been studied utilizing the thermal desorption with carbon dioxide as adsorbate: potassium carbonate/carbon black and silver/alumina. Supported catalyst surface area was determined for each system; the results were confirmed using physical mixtures of the two components (where the actual area of each component is known) and oxygen chemisorption for the silver/alumina system. The experimental technique allows for straightforward calculation of the catalyst area.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1939-1946 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Platinum supported on silica is used as a model supported catalyst for the purpose of demonstrating that the selective physisortion method yields the fractional catalyst surface area of supported catalysts, inclucing metal compounds catalysts for which the method is primarily intended. The selective physisorption results with nitrous oxide as adsorbate are compared with hydrogen chemisorption results for this purpose. Experimental and theoretical refinements of the method developed earlier in our laboratory are presented that allow rather accurate determination of the catalyst surface area. The refinements also make the method effctive even when the catalyst covers a small portion of the total surface area. Because of the nature of physisorption, the method should be applicable to any supported catalyst including metal compounds catalysts, provided a suitable adsorbate is used. Adsorbates other than nitrous oxide and carbon dioxide which are suitable for selective physisorption, are suggested.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 405-410 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general expression for the time-dependence of the activity of a catalyst pellet affected by both chemical deactivation and diffusion is developed. Specific results are given for both uniform and pore-mouth poisoning, with parallel and series poisoning mechanisms. Comparisons show a satisfactory agreement between theoretical and experimental results. A pellet effectiveness representing the combined effect of deactivation and diffusion is also developed in a form suitable for direct inclusion in reactor conservation equations.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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