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  • 1
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 1847-1859 
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The thermal oxidative stability of photocrosslinked high density polyethylene was studied. The relative effectiveness of various antioxidants (hindered phenols and amines, aromatic amine, organic sulfides, and phosphites) was examined by comparing the oxidation induction time (OIT) which was measured using differential scanning calorimetry. Hindered phenol antioxidants were found to be most effective. At an antioxidant concentration of 0.20 wt % which gave an OIT value of 20 min at 200°C, the photocrosslinking rate was decreased only to a limited extent as evidenced by a small drop in gel content. However, the efficiency of the antioxidants as stabilizers decreased to a considerable extent after the photocrosslinking process. Serious surface deterioration was found which was ascribed to depletion of antioxidant at the surface mainly due to high rate of oxidation and evaporation.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Microcolumn Separations 6 (1994), S. 515-524 
    ISSN: 1040-7685
    Schlagwort(e): electrospray ionization ; ion mobility detection ; ion mobility spectrometry ; liquid chromatography detector ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Electrospray ionization ion mobility spectrometry (ESI-IMS), a technique which has only recently become analytically useful, has been evaluated for use as a detector for microbore liquid chromatography and capillary electrophoresis. Figures of merit for ESI-IMS were determined. Detection limits as low as 1 × 10-15 mol s-1 were measured, with a linear response range of 3 to 4 orders of magnitude and with reproducibility within 3% (relative standard deviation of peak area). Gradient elution with water/methanol mobile phase did not perturb chromatographic baseline, compound response, or product ion mobility. Both positive and negative ion mobility spectra for more than 30 compounds demonstrated the sensitivity of ESI-IMS response to a wide range of analytes. Finally, the concept of using ESI-IMS as an ionization source for gasphase samples was presented, potentially unifying detector application for both gas and liquid chromatography.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    ISSN: 1042-7147
    Schlagwort(e): Benzophenone ; Ultraviolet light ; Gel content ; Tensile strength ; Young's modulus ; Elongation at break ; Creep behaviour ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Ultra high strength polyethylene (HSPE) fibers have been successfully photocrosslinked using benzophenone as photoinitiator. The introduction of photoinitiator without disturbing the fiber structure is a difficult problem which was solved by vapor absorption at elevated temperature while keeping the fiber under constant strain. The crosslinked fiber showed no decrease in mechanical properties at room temperature as is the case when fibers are crosslinked by other reported methods such as radiation and chemical crosslinking. The crosslinked fiber showed enhanced high temperature resistance as well as much lower creep rate on prolonged stressing. Photocrosslinking of HSPE fiber is superior to other crosslinking methods reported in the literature.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 2075-2080 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Three kinds of polyurethane (PU) and vinyl ester resin interpenetrating polymer network (IPN) have been synthesized to study their morphologies and mechanical properties for the potential application in the reinforced reactive injection molding process. For the PU prepared from uretonimine modified pure MDI, the macrophase separation of the IPNs between the rubber and plastic phases was found by DSC measurement and scanning electron microscopy (SEM) observation, whereas the interpenetration between the two networks was also observed on SEM photos at least around the area of interface. However, for the IPN systems including PU prepared from TDI or graft polyol, which was synthesized by using macromer technique, the compatibility between the two phases is excellent. The mechanical properties of these IPNs were measured and could be correlated well enough with their morphologies. The IPN prepared with graft polyol exhibited the best mechanical properties over all IPN specimens studied in this work. © 1992 John Wiley & Sons, Inc.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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