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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1973-1985 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Comparisons were made of differential scanning-calorimetric (DSC) thermograms of both liquid and powdered commercial phenol-formaldehyde resins. By a combination of the results from analyses under a variety of conditions, such as ambient pressure, high pressure, using freeze-dried samples, and also by direct observation of the resin-curing process in wood-veneer assemblies, the curing reactions of phenol-formaldehyde resins were found to differ for resol and novolac systems. At a heating rate of 10°C/min, the resol resin showed endothermic curing reactions at temperatures of about 150°C, while the novolac-type resin showed an exothermic peak maximum at about 160°C. Results are presented to show how DSC can be used to differentiate between a resol and novolac system.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 215-225 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Acetylation of phenol-formaldehyde (PF) wood adhesives afforded derivatives which could be characterized by proton magnetic resonance (PMR) spectroscopy. Through use of the chemical shift and integral parameters, relative comparisons were made for the degree of polymerization of resins prepared with different molar ratios. Additionally, PMR studies of these acetylated derivatives provided a means of determining methylol content and number of aromatic protons remaining, and to some extent gave an estimate of molar formaldehyde-to-phenol ratio. Experiments conducted with Ca(OH)2 and NaOH as catalysts showed the latter to be the more effective catalyst for PF systems.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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