ISSN:
1022-1352
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Four ethylene-1-decene copolymers, covering a wide range of compositions, were analyzed in solution by means of 13C NMR spectroscopy. A detailed assignment of the signals to the different triad sequences was carried out. The experimental triad distributions were compared with calculations assuming Bernouillian and first-order Markov statistics, finding a better agreement for the latter model. The triad distributions were also used for the determination of the reactivity ratios of the two comonomers.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1994.021950714
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