ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The title reactions have been investigated in a static system. The addition of acetylene to cyclopentadiene (CPD) results in formation of norbornadiene (BCH), cycloheptatriene (CHT), and toluene (T), while BCH decomposition produces CPD, C2H2, CHT, and T. Kinetic studies, comprising both product-time evolution and initial pressure variation, support a mechanism These reactions are almost certainly homogeneous and molecular in nature. Least mean square analysis of the data yield for temperatures of 525-656°K, log k-1 (1./mole·s)=7.51±0.05- (24.19±0.15 kcal/mole)/RT ln 10, and for temperatures of 584-630°K, \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_1 (s^{ - 1}) = 14.78 \pm 0.10 - (51.37 \pm 0.29\,kcal/mole)/RT\ln 10 $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_1 (s^{ - 1}) = 14.90 \pm 0.11 - (51.36 \pm 0.30\,kcal/mole)/RT\ln 10 $$\end{document}
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550070302
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