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  • 1970-1974  (3)
  • 1955-1959
  • Chemistry  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 8 (1974), S. 3-10 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Strength, dimensional change during setting, and corrosion resistance have been measured for amalgams prepared from splat-cooled alloys of different compositions in the Ag-Sn-Cu system. The amalgam with optimum values of these properties was made from the alloy containing 60 at. % Ag, 25 at. % Sn, and 15 at. % Cu. Tensile strengths for amalgams from this alloy were about 8000 psi, dimensional change during setting near zero, and corrosion resistance was good.X-Ray diffraction showed that the γ1 and γ2 phases formed during the early stages of setting but that the γ2 phase had essentially disappeared after about 24 hr. At the latter time Cu6Sn5 was present.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 4 (1970), S. 269-274 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The extraordinary stability of the γ1 phase of dental amalgam was believed to indicate that part of the Sn in dental amalgam was contained in this phase. By extending the Hume-Rothery “electron compound” ideas to the three component Ag-Sn-Hg system, an estimate was made of the amount of Sn which could be held in the γ1 structure.A Ag-Sn alloy containing 9.1 weight per cent Sn was prepared, spheroidized, and sized. Portions were amalgamated and molded into tensile specimens, parts of which were subjected to X-ray diffraction, corrosion tests, and tests to determine amalgamation rate and dimensional changes during setting.X-ray diffraction patterns showed a complete absence of the γ2 phase, (thus indicating that all Sn was in the γ1 phase) and a stability intermediate between γ Ag-Hg and the γ1 phase of dental amalgam. Physical tests showed a low amalgamation rate, low 1-hr strength, high 7-day strength, and high corrosion resistance.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 239-244 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Spherical-particle Ag-Sn alloy powders containing 4.3, 8.3, 12.0, 15.4, 18.5, 21.4, and 24.1 atomic per cent Sn were obtained. Amalgams from these alloys were examined by x-ray diffraction and metallography for the presence of the γ2 phase and the γ1 → β1 phase transformation. A single amalgam of the approximate composition of dental amalgam was prepared from a melt at high temperature and pressure and likewise examined.Results showed that the solubility of Sn in Ag-Hg is about 7 atoms of Sn per unit cell of the γ phase. As clinically prepared, the γ1 phase of dental amalgam contains, however, only about 5 atoms of Sn per unit cell. These 5 atoms, nevertheless, result in a very considerable stabilization of this phase due to the increase in its electron concentration.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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