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  • 1965-1969  (1)
  • Chemistry  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 349 (1967), S. 213-219 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Für die Hydrazin-Komplexe von Mn(II), Co(II), Ni(II), Cu(II) und Zn(II) werden Zusammensetzung und Bildungskonstanten nach der Methode von Rossotti und Rossotti ermittelt, wobei experimentell pH-Titrationen in Lösungen durchgeführt wurden, die Metall-perchlorat, Hydrazin-diperchlorat und Natriumperchlorat (Ionenstärke μ = 1, t = 30°C) enthalten. In entsprechender Weise wurden die Bildungskonstanten für die Protonisierung von Hydrazin bestimmt. Selbst bei den höchsten Verhältnissen: Gesamt-Hydrazin/Gesamt-Metall (etwa 60) haben die höchsten Komplexe nur bei Co(II) und Zn(II) das Verhältnis:Metall/Hydrazin = 1 : 2, während in allen anderen Fällen in Lösung nur 1 : 1-Komplexe zu existieren scheinen.Die Werte der Bildungskonstanten (30°C, μ = 1) siehe „Summary“.Die nach Bjerrum berechneten β1-Werte sind mit den gefundenen in recht guter Übereinstimmung mit Ausnahme für Co(II). Die Grenzen für die Bjerrum-Methode werden diskutiert.
    Notes: The compositions and formation-constants of the complexes formed by Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with hydrazine have been evaluated graphically following the method of Rossotti and Rossotti using the necessary data from the results of pH titration of solutions containing the metal perchlorate, hydrazinium diperchlorate and sodium perchlorate at an ionic strength of unity at 30°C. The values of the successive equilibrium constants for the protonation of hydrazine, which were also needed, have been evaluated separately by similar procedure. Even at the rather high ratio of ca. 60 of (total hydrazine)/(total metal) the highest complexes which appear to be formed in the systems investigated have the ratio of metal:hydrazine of 1:2 for Co(II) and Zn(II), while in all the other cases only 1: 1 complexes appear to exist in solution.The values of the formation-constants (at 30°C; μ = 1) obtained are: \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{l} \log \beta _1 :{\rm Mn(II), 4}{\rm .76; Co(II), 1}{\rm .78; Ni(II),3}{\rm .18; Cu(II),6}{\rm .67;Zn(II), 3,69}{\rm.} \\ \log \beta _2 :{\rm Co(II), 3}{\rm .34; Zn(II), 6}{\rm .69}. \\ \end{array} $$\end{document}β1 values obtained from the Bjerrum relation are in fairly good agreement with those given above except for Co(II). The limitations of Bjerrum's method are discussed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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