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  • 1
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 479-503 
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The preparation of a variety of silicon-containing epoxy monomers and oligomers is described and their reactivity in photoinitiated cationic polymerization examined. Monomers and oligomers having terminal cycloaliphatic epoxy groups were found to be especially reactive in cationic polymerization. These materials are attractive candidates for use in coatings, adhesives, and elastomers.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1197-1215 
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This first paper on the topic of polydimethylsiloxane-vinyl block polymers describes the development of a unique class of vinyl functional silicon containing free-radical initiators which can be used in the synthesis of block polymers. Details of the synthesis and characterization of these initiators are described together with the kinetics of their thermolysis. Specific conditions are described under which these initiators can be condensed with α,ω-hydrogen functional polydimethylsiloxane oligomers by a platinum-catalyzed hydrosilylation reaction to yield macroinitiators.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The thermolysis of polydimethylsiloxanes containing thermally labile bis(silyl pinacolate) groups in the backbone in the presence of various vinyl monomers leads to the direct synthesis of block polymers. Depending on the monomer chosen, simple triblock or multisequence block polymers can be readily prepared. Analysis of the products of the block polymerizations using various styrenic-type monomers shows that only block polymers are obtained, i.e., no homo-polymers are formed. These block polymers display evidence of phase separation such as intense iridescence and solvent-dependent mechanical properties. The mechanical properties of these block polymers have been measured and found to be highly composition dependent. Depending on the block length and the relative portions of the hard (vinyl) and soft (polydimethylsiloxane) blocks, one can produce either thermoplastic elastomers or rubber-modified thermoplastics.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 3293-3309 
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: All aromatic polyimides bearing diarylsulfide linkages in the main chain were prepared either by condensation of a sulfur containing dianhydride with an aromatic diamine or the condensation of a sulfur containing aromatic diamine with a dianhydride. Phenylation with diphenyl iodonium salts was then used to convert the diarylsulfide groups to triarylsulfonium salts. The resulting photosensitive polyimides were shown to undergo main chain cleavage during photolysis using UV irradiation. These new polyimides are candidates for positive working, high temperature photoresist materials.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3951-3968 
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This paper describes the synthesis and characterization of a series of (4-alkoxyphenyl)phenyliodonium salts which are excellent photo- and thermal-initiators for the cationic polymerization of vinyl and heterocyclic monomers. These compounds are easily prepared by straightforward synthetic techniques and display very good solubility and photoresponse characteristics which make them especially attractive for use in UV curing applications. Those compounds with alkoxy chains of eight carbons and longer are essentially nontoxic.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 28 (1990), S. 323-329 
    ISSN: 0887-6258
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 57 (1995), S. 1005-1011 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: We have successfully prepared Congo Red-based polyurethane ionomers at our lab, and these ionomer structures have been proven by infrared (IR) spectra. For a dye-based polyurethane ionomer molecule solution, the surface tension was found to decrease, but the number-average particle size was found to increase with increasing concentration of Congo Red employed to prepare this ionomer molecule. Interestingly, the number-average particle size of dye-based polyurethane ionomer molecules decreases with increasing concentration of Congo Red in the presence of other dyes (i.e., Remajol Brilliant Blue R and Amaranth), as a result of Congo Red intramolecular interaction. It is important to point out that the addition of a fixed concentration of Amaranth to prepare Congo Red-based polyurethane ionomer molecules will significantly enhance the tensile strength but will decrease the elongation of this ionomer molecule. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 561-563 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 1041-1046 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Various methods of hydrogenating ring opening metathesis polymerization (ROMP) polymers were investigated as part of an effort to improve their stability and increase their usefulness as matrix materials for nanocluster synthesis. Hydrogenation with Pd/BaSO4 catalyst in high-pressure hydrogen gas was only partly successful and limited to unfunctionalized polymers such as polymethyltetracyclododecene. Block copolymers containing phosphine or carboxylic acid functionalities were successfully hydrogenated by diimide generated in situ from p toluenesulfonylhydrazide. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 2265-2271 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: PV Fast Maroon HFM based polyurethane ionomers were successfully synthesized at our lab, and these ionomer structures have been proven by infrared spectra. In aqueous solution, the surface tension was found to be lower for the HFM pigment-based polyurethane ionomer made by toluene diisocyanate (TDI), as a result of more hydrophobicity adsorbed at the surface of aqueous solution. The viscosity decreases with increasing the concentration of the HFM pigment used to prepare the HFM pigment based polyurethane ionomer, indicating that the structure of this ionomer is possibly considered to be a type of micelle. In addition, the number-average particle sizes are seen to be decreased with increasing the concentration of HFM pigment employed for making the HFM pigment based polyurethane ionomer. These results also suggest that the HFM pigment based polyurethane ionomer molecule could have a micelle-like sturcture. However, the 100% modulus property for both the IPDI type or the TDI type of PV Fast maroon HFM based PU ionomer molecules appears to increase gradually with increasing the concentration of HFM, as a result of more crosslinking formed. ©1996 John Wiley & Sons, Inc.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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