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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of fracture 86 (1997), S. 289-300 
    ISSN: 1573-2673
    Keywords: Polymers ; crack tip ; displacement fields ; moiré interferometry ; PMMA ; PA6/PPE/SBS alloy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Moiré interferometry was utilized to experimentally determine displacement fields around a crack tip in single-edge-cracked tensile PMMA and PA6/PPE/SBS alloy specimens. Vertical displacement v was expressed as functions of distance r and angle θ from the crack tip, and compared with the approximate solution of linear elastic fracture mechanics to study its applicability to polymers. The results showed that the solution agreed with the experiments in the vicinity of a crack tip in the PMMA specimens, but it yielded a discrepancy as r increased. For the alloy specimens, however, the solution gave much smaller values than the experiments. The principle of superposition was employed to determine the values of v*(=v-v′), i.e. the difference between two displacements v and v′ which was related to a uniform strain field without a crack. The expressions for v* and v were also introduced to analyze the effects of r, θ and load P applied to the specimen. v* was found to be an important factor in increasing the displacements near the crack tip, and the v expression well represented the experimental results for both the PMMA and alloy specimens.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of fracture 83 (1997), S. 305-313 
    ISSN: 1573-2673
    Keywords: dynamic crack propagation ; stress intensity factor ; crack velocity ; a cceleration ; polymers ; PMMA ; expoxy ; caustic method.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Dynamic crack propagations in PMMA and epoxy specimens were studied using the method of caustics in combination with a Cranz-Schardin type high-speed camera. Single-edge-cracked tensile specimens were fractured under pin-loading conditions so that cracks could experience acceleration, deceleration and re-acceleration stages in one fracture process. The dynamic stress intensity factor K ID, crack velocity a and acceleration a were evaluated in the course of crack propagation to examine the effects of a and a on K ID. Results showed that a and a were important factors in changing the values of K ID, and for constant a the decelerating crack had a larger value of K ID than the accelerating or re-accelerating crack. Also, it was found that K ID could be expressed as two parametric functions of and a for PMMA and epoxy specimens.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of fracture 96 (1999), S. 347-360 
    ISSN: 1573-2673
    Keywords: Dynamic crack propagation ; unloading behavior ; stress intensity factor ; crack velocity ; unloading rate ; brittle polymers ; epoxy ; PMMA ; homalite-100 ; caustic method.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The method of caustics in combination with a Cranz–Schardin high-speed camera was utilized to study dynamic crack propagation and unloading behavior of epoxy, PMMA and Homalite-100 specimens. Dynamic stress intensity factor K ID and crack velocity $$\dot a$$ were evaluated in the course of crack propagation. Caustic patterns at the loading points were also recorded to estimate load P applied to the specimen. Unloading rate $$\dot P$$ , the time derivative of P, was determined as a function of time t, and its time correlation with K ID or $$\dot a$$ was examined. The findings showed that the change in $$\dot P$$ was qualitatively in accord with the change in K ID or $$\dot a$$ . However, there existed slight differences among the values of t giving the maximum $$\dot P$$ , $$\dot a$$ and K ID, so that their order was $$\dot a$$ , $$\dot P$$ and K ID.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 25-32 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrasonic fractography studies were performed on poly(methyl methacrylate) of high molecular weight. The transient fracture velocity change at the slow-to-fast transition during discontinuous propagation has been measured precisely. Fast fracture starts with a characteristic velocity which falls in a narrow range between 90 to 150 m/s, nearly independent of the loading speeds and the specimen temperature from -50 to 40°C. Parallel double-cantilever-beam specimens exhibited stick-slip type propagation whose velocity change was also evaluated. In these specimens, the fast fracture abruptly slows down to speeds on the order of 10° m/s. These intermediate velocities have never been obtained in the slow-to-fast transition. Velocity measurements under hydrostatic pressure have shown that fracture velocities decrease significantly with increasing pressure, and that the slow-to-fast transition tends to disappear at a pressure between 5 and 10 MPa. Models have been presented concerning the mechanism of the slow-to-fast transition, crazing and cracking under superposed cyclic stress field, and the relationship between dynamic toughness and fracture velocity in this material.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 1141-1152 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 27 (1988), S. 1917-1925 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Adiabatic differential scanning microcalorimetry, which provides curves of the heat capacity vs temperature, was carried out for the DNA of plasmid pJL3-TB5 (5277 base pairs in length). The calorimetry curve shows nine peaks ranging from 81 to 96°C in 1 × SSC buffer at a heating rate of 0.25°C, due to the stepwise helix-coil transition of the DNA along the molecular chain. The theoretical melting curve, which can be constructed by calculation from the entire nucleotide sequence of the plasmid DNA by the helix-coil transition theory, is then compared with the calorimetry curve. The two curves resemble each other remarkably well, particularly when a parameter for the methylated adenine residues at GATC sites by Dam methylase is used appropriately. This allows us to assign each peak in the calorimetry curve to the melting of the respective regions of the plasmid DNA sequence. The local stability of the helix-coil transition along the DNA chain is closely related to the functional regions coded by pJL3-TB5, such as genes, transcriptional promoters, and particular sites generated by recombination of two different sequences in vivo and in vitro.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 711-717 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The degradation of the surface composition of poly(ethylene terephthalate) (PET) film by ultraviolet light was analysed by ESCA combined with gas chemical modification (GCM) techniques. A new approach for distinguishing phenolic hydroxyl and alcoholic hydroxyl groups was presented, which uses the difference in reactivity of trifluoroacetic anhydride to the phenolic group and to the alcoholic group. The carboxyl group was detected with trifluoroethanol. The ESCA-GCM results showed differences of the chemical composition of the light-facing side and the back side of the PET film. According to photodegradation mechanisms of PET reported by other researchers, carboxyl group formation suggested cleavage of the main chain of PET. The number of the phenolic carbon on the light-facing side corresponded to the existence of 16 phenolic groups per 100 monomeric units.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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