ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Reactions of μ-Distibane- and Di-μ-antimonido-bridged Metalcarbonyl Complexes of Chromium, Molybdenum, and TungstenBy irradiation of hexacarbonylmolybdenum in tetrahydrofuran solutions are produced, which react with tetramethyl-, -ethyl-, and -phenyldistibane to yield the complexes (CO)5MoSbR2SbR2Mo(CO)5, R = Me, Ph and (CO)4Mo(SbR2)2Mo(CO)4, R = Me, Et, Ph.(CO)4W(SbPh2)2W(CO)4 is a product of the thermal reaction of hexacarbonyltungsten and tetraphenyldistibane. Cleavage of (CO)5CrSbMe2SbMe2Cr(CO)5 with bromine yields (CO)5CrSbMe2Br.
Notes:
Durch Bestrahlen von Hexacarbonylmolybdän in Tetrahydrofuran erzeugte Lösungen reagieren mit Tetramethyl-, -ethyl- und -phenyldistiban zu den Komplexen (CO)5MoSbR2SbR2Mo(CO)5, R = Me, Ph und (CO)4Mo(SbR2)2Mo(CO)4, R = Me, Et, Ph.(CO)4W(SbPh2)2W(CO)4 entsteht thermisch aus Hexacarbonylwolfram und Tetraphenyldistiban. Die Spaltung von (CO)5CrSbMe2SbMe2Cr(CO)5 mit Brom ergibt (CO)5CrSbMe2Br.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19814770615
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