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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 274 (1996), S. 801-804 
    ISSN: 1435-1536
    Keywords: Multihollow particles ; emulsion polymerization ; morphology ; carboxyl group ; alkali swelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Submicron-sized styrene-methacrylic acid copolymer particles, which were produced by emulsion copolymerization, were changed to those having multihollow structure by treating stepwise the emulsion as follows. First alkali treatment was carried out at higher temperature than the glass transition temperature and subsequently the emulsion was cooled by keeping it at room temperature. This was named “alkali/cooling method”. The effects of methacrylic acid content, pH, time and temperature in the alkali treatment on the formation of multihollow structure were clarified.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 275 (1997), S. 82-85 
    ISSN: 1435-1536
    Keywords: Key words Multi-hollow particle ; emulsion polymerization ; morphology ; carboxyl group ; alkali swelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  The effects of molecular weight, particle diameter and cooling condition on the formation of multi-hollow structure formed within submicron-sized styrene-methacrylic acid copolymer particles by the “alkali/cooling method” proposed by the authors were examined and the formation mechanism was proposed. The original particles were produced by emulsion copolymerization in the presence of n-octyl mercaptan as a chain transfer agent.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1435-1536
    Keywords: Multihollow particles ; emulsion polymerization ; morphology ; carboxyl group ; transition temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Submicron-sized multihollow styrene-methacrylic acid (92.6/7.4, molar ratio) copolymer particles having high transition temperature above 100°C were produced by using the stepwise alkali/acid method proposed by the authors. The original particles were prepared by emulsion copolymerization of styrene and methacrylic acid. The effects of pH, temperature and time in the alkali treatment process as the first step on the multihollow structure were clarified under the same acid treatment conditions.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 487-496 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mar-resistant coating system was obtained by screening combinations of silicone and vinyl compounds. It was found that binary systems, such as the γ-glycidoxypropyltrimethoxysilane-glycidyl methacrylate system, were excellent not only in mar resistance but also in adhesion to base resin polymers. Haze values of these coatings, after the sand-falling test, reached less than 10%. The coating process consisted of three steps: the preparation of prepolymer, the coating to plastic surface, and the curing of the coating by heating. It was found that the prepolymerization step could be performed by irradiation very conveniently; the control of viscosity for coating application and thickness control could be possible without any gel formation. These coatings were also good in weather resistance due perhaps to the good adhesion to base resin and could be applicable to plastic spectacles, glazing materials, and a variety of other products.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 6 (1968), S. 727-732 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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