ISSN:
1434-1948
Keywords:
Molybdenum
;
μ-Oxo
;
Conformational equilibrium
;
X-ray diffraction
;
NMR spectroscopy
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A new thiocyanatomolybdenum(VI) dioxo-μ-oxo complex dimer bearing a 4,4′-di-tert-butyl-2,2′-bipyridine ligand (2) is shown to exist in the crystal cell unit as a meso (Mo-O-Mo angle of 180°) and d,l, pair (Mo-O-Mo angle of 155.7°). These conformers are in equilibrium in solution and have been observed clearly by 1H NMR spectroscopy.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
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