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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 26 (1901), S. 452-453 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 149-150 
    ISSN: 0935-6304
    Keywords: Liquid Chromatography, HPLC ; Ion pair reverse phase gradient technique starting at low pH ; Viral associated glycosoaminoglycans, G2 and G4 separated ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 1 (1978), S. 177-178 
    ISSN: 0935-6304
    Keywords: Liquid Chromatography, HPLC ; Analysis of methods for proteins and peptide separation and yield ; Reverse phase, ion exchange, molecular exclusion ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New methods for peptide separation are being developed. Resolution of peptide mixtures on HPLC with good reproducibility indicates the progress that has already been made in development of supports with useful separation capabilities. At present adsorptive characteristics of the stationary phases may place limitations on the applicability of the technique to underivatized peptides. Hopefully, the application of ionpairing techniques and the development of new support materials will expand the range of application for protein and peptide purification.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 30 (1987), S. 970-977 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Actual laboratory data obtained from steady-state Dunaliella tertiolecta cultures grown under a wide range of photon flux densities were used in a simple model to calculate daily production in a conventional algal mass culture system. In spite of large physiological and biochemical variations between low-light- (LL) and high light- (HL) adapted cultures, the overall calculated daily productivity is almost identical for both strains grown at optimal conditions. When production of fine biochemicals is considered, however, a hypothetical HL strain, which cannot shade adapt, is advantageous. Based on biochemical and biophysical analysis of D. tertiolecta responses to growth irradiance levels, specific targets are defined for genetic manipulation to enhance productivity in algal mass culture systems. The targets identified are (1) amplification of the carboxylation enzyme ribulose-1,5-bisphosphate carboxylase-oxygenase relative to the electron transport complexes, which should increase photosynthetic capacity at light saturation, and (2) enlargement of the light-harvesting complexes by varying their pigment composition in order to increase light harvesting at low photon flux densities.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 418-422 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 25 (1900), S. 265-269 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Laser microprobe mass spectrometry (LMMS) has been applied systematically to a variety of organic polyfunctional molecules, covering a wide range of structures and polarities. The microprobe generally offers a combination of desorption under relatively mild conditions with abundant fragmentation. We attempted an empirical approach by tentative hypotheses about desorption and ionization in LMMS to consistently rationalize the detected fragments. The complementary nature of structural data, carried by positive and negative ions, is characteristic for LMMS results of non-ionic compounds. The analysis of salts represents, traditionally, an ultimate test case for soft methods in organic mass spectrometry. Hence, by a selected series of compounds, we have tried to assess to which extent the presence of preformed ions becomes an asset for LMMS analysis and affects the amount, the accessibility or the distribution of organic information between positive and negative fragments.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Laser microprobe mass spectrometry (LMMS) has been used to systematically study polyfunctional molecules, covering a wide range of structure and polarity. The knowledge about the mechanisms actually involved for desorption and ionization (DI) of organics by laser microbeam irradiation of solid samples at high-power density is rather limited. Therefore we have elaborated a set of tentative hypotheses about DI in LMMS, permitting consistent rationalization of detected signals. The technique apparently combines desorption under mild conditions, shown by the release of intact thermolabiles, with extensive fragmentation. Structural data are typically distributed between cations and anions. Interpretation of negative-ion detection mode mass spectra often represents intricate problems, partly due to the lack of sustaining background information from conventional mass spectrometry. Selected examples are presented to illustrate the occurrence of electron capture ionization, the role of heteroatoms in the formation of negative ions and the tendency to undergo complex skeletal rearrangements. Although LMMS was originally aimed at microprobe applications, it has been found to be a valuable tool in organic mass spectrometry.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 1 (1969), S. 319-327 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The NMR spectra of fifteen para-substituted acetanilides, XC6H4·NH·CO·CH3 (X = NH·CO·Me; NH2; CO·OEt; COOH; Cl; OEt; F; H; OMe; CH3; NO2; C6H5; —N=N—C6H5; Me3Si), have been recorded. δCH3 and δNH are linearly related to Hammett's σp constant. The coupling J (o-H—H) between aromatic protons is mainly dependent on σR0. J(13C—H), in methyl group is approximatively constant in the series.
    Notes: Les spectres de RMN de quinze acétanilides para-substitués XC6H4·NH·CO·CH3 (X = NH·CO·ME; NH2; CO·OEt; COOH; Cl; OEt; F; H; OMe; CH3; NO2; C6H5;—N=N—C6H5; Me3Si) ont été étudiés. Il y a une relation linéaire entre δCH3 et δNH et les constantes σP de Hammett. Le couplage J(o-H—H) entre les protons aromatiques est relié plutôt à σR0. La constante J (13C—H) dans le groupe CH3, est indépendante de X.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 15 (1990), S. 651-658 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: 252-Cf particle-induced desorption mass spectrometry (PDMS) has been used to follow the modification of chrysotile asbestos fiber with organosilane compounds. Monitoring changes in the peak area ratios of Si+, Mg+ and SiOH+ ions in PDMS and atomic ratios from XPS, the formation of organosiloxane polymers vertical to the surface is suggested. Changes in the ratios also indicate differing coverages of the modifiers, owing in part to steric effects associated with the different organic substituents. The fibrous, non-conductive nature of the sample did not impair the analysis with 252-Cf PDMS. This application lends further support to the belief that PDMS is a surface-sensitive technique.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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