ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of labeled N15NO+ with CO, NO, O2, 18O2, N2, NO2, and N2O have been investigated using a tandem ICR instrument. In each case the total rate coefficient, product distribution, and kinetic energy dependence were measured. The results indicate that very specific reaction mechanisms govern these reactions. This conclusion is suggested by the lack of isotopic scrambling in many cases and by the complete absence of energetically allowed products in almost all of the systems. The kinetic energy studies indicate that most of the reaction channels proceed through an intermediate complex at low energies and via a direct mechanism at higher kinetic energies. Such direct mechanisms include long range charge transfer and atom or ion transfer.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550160608
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