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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 996-1001 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Weldlines are fatal defects in many injection moldings of thermosetting resins and thermoplastics. Significant strength reduction by weldlines in thermoplastics is caused by poor adhesion, molecular orientation, and a V-notch effect. These factors have been little investigated in detail, in spite of being well known. In the present article, the V-notch effect on strength is discussed for two types of thermoplastics, polystyrene and polycarbonate. The depth of weldlines was obtained by milling on the weldline surface, and the fracture toughness was measured with a double edge notched specimen. Polystryrene, which was drastically weakened by weldlines, had relatively deeper V-notch regions and the fracture toughness was also reduced by weldlines. Although polycarbonate had the same fracture toughness as polystyrene, it had strong weldlines since the depth of weldlines was negligibly small.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 2387-2393 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The permeability (P) of cellulose nitrate (CN)/poly(ethylene glycol) (PEG) blend membranes for N2, O2, and CO2 has been measured as a function of film composition. The system CN/PEG-300 showed excellent miscibility, and films of the composition from 100/0 to 50/50 could be used for permeability measurements. P for each gas has been found to be almost constant or rather slightly lowered up to ca. 20 wt % PEG-300 content and then increased appreciably with increasing fraction of PEG. The increment of permeability was most remarkable for CO2, and hence the permselectivity for CO2 was considerably enhanced. Such a behavior of P has been found to be attributable to the plasticizing effect of PEG molecule lowering the glass transition temperature of the blend polymers. The effect of the molecular weight of PEG and that of closed voids generated in glassy blend membranes fabricated from acetone cast on gas permeabilities have been also discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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