ISSN:
0268-2605
Keywords:
Polysaccharide
;
Dextran
;
Organotitanium
;
Organotin
;
Metal-containing carbohydrate polymers
;
Phase transfer catalysis
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Phase transfer catalyzed interfacial reaction of the polysaccharide dextran (C6H10O5)n with organotitanium and organotin dichlorides to form metal-containing carbohydrate polymers has been carried out in the presence of two bases, sodium hydroxide and triethylamine. Interfacial systems employing sodium hydroxide with a crown ether phase transfer catalyst (PTC) gave generally greater yields compared with the analogous systems without a PTC. The trend of maximum yield for triethylamine systems with organotin dichloride not containing a PTC was different from that observed for the sodium hydroxide systems without a PTC, probably because of the ability of triethylamine to act as a PTC.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590010306
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