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  • 1
    Electronic Resource
    Electronic Resource
    Solution viscosity and molecular weight of polystyrene prepared by aluminium chloride catalysis (1952)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 9 (1952), S. 286-288 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1952.120090312
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  • 2
    Electronic Resource
    Electronic Resource
    Interaction of proflavine and 9-aminoacridine with DNA at temperatures below and above the melting temperature (1971)
    New York : Wiley-Blackwell
    Biopolymers 10 (1971), S. 399-410 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The influence of temperature on the binding of 9-aminoacridine and of proflavine to E. coli DNA in 10-3M NaCl solution has been determined by a spectrophotometric technique. The inadequacy of the expression normally used for the determination of the extent of binding is discussed with reference to measurements at temperatures above which dissociation of the double helix occurs. A method of determining the relative extents of binding to native and denatured DNA at elevated temperatures is described.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360100214
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  • 3
    Electronic Resource
    Electronic Resource
    The kinetics of the renaturation of deoxyribonucleic acid denatured in the presence of copper (II) ions (1972)
    New York : Wiley-Blackwell
    Biopolymers 11 (1972), S. 1661-1684 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: DNA which has been heat denatured in the presence of Cu++ ions can be completely and rapidly renatured by increasing the ionic strength of the solution above a critical value. A kinetic study of this renaturation recation was carried out by following the associated UV absorbance change and also by following the change in free Cu++ ion concentration by means of a specific Cu++ ion activity electrode. The data obtained could be fitted to first-order kinetics for a considerable extent of the reaction and the rate constant was found to increase with temperature and ionic strength, but to decrease markedly as the bulk viscosity of the solution was increased. At temperatures greater than 5°C the reaction rate depended on the time elapsing between denaturation and the commencement of the renaturation reaction. As there was good agreement between the rate constants obtained by following the decrease in hyperchromism and by following the increase in free Cu++ ion concentration, it is concluded that under the conditions employed, the rate of renaturation is determined by the rate of release of Cu++ ions from the denatured DNA-Cu++ complex.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1972.360110812
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  • 4
    Electronic Resource
    Electronic Resource
    High speed molecular weight distribution (1975)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 831-833 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is now possible to do molecular weight distribution of polymeric material almost as fast as you can put them in solution. μSYRAGEL® has opened a new era in the determination of molecular weight distribution of polymers. With operational efficiencies of 800 plates/min., one can obtain a molecular weight distribution in 15 mins. Combining three of the newest advances in liquid chromatography - solvent delivery, septumless injection, and μSYRAGEL - now makes it possible to use molecular weight distribution as a quality control tool in polymerization and fabrication. The reproducibility of the molecular weight distribution is now good enough that overlays can be done from the raw data. The chromatograms can be used right off the recorder. The reproducibility of the weight average and number average molecular weight is 2-3 percent.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760151203
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  • 5
    Electronic Resource
    Electronic Resource
    The sedimentation and diffusion of sodium polymethacrylate and polymethacrylic acid (1954)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 12 (1954), S. 209-219 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The sedimentation constants and diffusion coefficients of sodium polymethacrylate and of polymethacrylic acid have been determined at various concentrations of polymer and of added electrolyte and the nature of the charge effects is considered. A ratio y = (molarity of added electrolyte)/(grundmolarity of polymer) is used to obtain S20 at y = ∞ when the polyelectrolyte is assumed to be uncharged. The variation of the effective radius with y is considered not to be due to asymmetry but to the open network nature of the polyelectrolyte coil.The sedimentation constant of unionized polymethacrylic acid is determined and also the variation of sedimentation constant with degree of ionization.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1954.120120117
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  • 6
    Electronic Resource
    Electronic Resource
    Hydrodynamic properties of polyelectrolytes. Part I. Poly-4-vinyl-N-n-butylpyridinium bromide (1956)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 21 (1956), S. 463-472 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The viscosity, streaming birefringence, and sedimentation of a sample of poly-4-vinyl-N-n-butylpyridinium bromide have been measured in aqueous and in sodium chloride solutions. The theory of Peterlin for concentrated solutions has been found to be in agreement with the results. Values of the molecular weight have been calculated by different methods and a value of 9 × 105 has been chosen.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1956.120219910
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  • 7
    Electronic Resource
    Electronic Resource
    Hydrodynamic properties of polyelectrolytes. Part II. Poly-4-vinylpyridine (1956)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 21 (1956), S. 473-482 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The hydrodynamic properties of fractionated samples of poly-4-vinylpyridine have been studied. The intrinsic viscosities and the Huggins' constant (k′) have been obtained. The effect of shear on the viscosity disappears at high dilution. The sedimentation constants (S0) have been measured, and the streaming birefringence has been investigated at various concentrations and shear gradients. The Peterlin theory for concentrated solutions is in good agreement with the results for the orientation angle, but is not so well in accord with the magnitude of the birefringence. The partial specific volume is low (0.685). Molecular weights have been calculated for the fractions, and it is concluded that the shape of the molecules in solution approximates to that of a stiff coil.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1956.120219911
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  • 8
    Electronic Resource
    Electronic Resource
    Concentration dependence of the reduced viscosity of dilute aqueous polyelectrolyte solutions (1965)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 3 (1965), S. 1941-1948 
    Details
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The concentration dependence of the reduced viscosity has been studied for several polyelectrolytes in conductivity water. It is shown that the viscosity maximum previously reported for polyelectrolyte solutions without added electrolyte can be explained either by the presence of ionic impurities in the solvent or by the contamination of the solutions. It is concluded that the folding chain theory of polyelectrolyte solutions requires amendment to account for the experimental results on counterion association. A suggested amendment to the theory implies that the application of the Huggins equation to the concentration dependence of polyelectrolyte solutions in the presence of added electrolyte may not lead to information concerning the interactions between the polyions in solution.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1965.100030523
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