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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 24 (1982), S. 837-845 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Alcohol dehydrogenase has been immobilized to the basic copolymer and its several derivatives using various techniques. Enzyme coupling to the supports with amino groups by means of glutaraldehyde was found the most suitable. Activity of alcohol dehydrogenase coupled to these amino supports was comparable to that of the enzyme bound to Sepharose. Thermal and pH stability of alcohol dehydrogenase increased essentially upon immobilization. Kinetic properties of the immobilized enzyme differed from those of free alcohol dehydrogenase, pH optimum shifted to alkaline range, and apparent Michaelis constants for substrates and coenzymes increased. Curvatures observed in Lineweaver-Burk plots for coenzymes suggest an involvement of diffusion effects in the reaction catalyzed by alcohol dehydrogenase linked to these polymers.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 48 (1993), S. 1731-1737 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dependence of phase structure on the intensity of mixing was studied for two modified polyamide/[poly(phenylene oxide) + polystyrene] (50/50) blends with different viscosity ratios of components. In these blends, polyamide forms the matrix and the mixture of miscible polymers [poly(phenylene oxide) and polystyrene] forms the disperse phase at all rates of mixing. The average size of the droplets of the disperse phase grows with increasing rate of mixing. This (rather surprising) result is explained as a consequence of the dynamic equilibrium between breakup and coalescence of droplets in a highly concentrated system at the condition of steady mixing. Generally, the dependence of droplet size on rate of mixing is not necessarily a monotonic function for blends with a high content of the disperse phase. © 1993 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die abhängigkeit der Grenzviskositätszahl von der Molekülmasse für Poly(phenyl-sila-sesqui-oxan) mit einem geringen Gehalt der bifunktionellen Gruppen (CH3)2SiO und Ph2SiO wird auf Grundlage der für steifkettige Polymere entwickelten Theorie interpretiert. Angeäherte Werte der statistischen Segmentlänge werden ermittelt und diskutiert.
    Notes: The dependence of intrinsic viscosity on the molar mass of ladder-like poly(phenyl-sila-sesqui-oxane)s containing a small amount of bifunctional units, (CH3)2SiO and Ph2SiO, is interpreted in terms of the theory developed for stiffchain polymers. Approximate values of the Kuhn segment length are estimated and discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Einfluß von Gehalt und Typ des linearen Polyethylens, des EPDM-Kautschuks und des Verarbeitungsverfahrens auf die mechanischen Eigenschaften von ternären Mischungen Polypropylen/EPDM-Kautschuk/Polyethylen wurde untersucht. Mischungen von EPDM-Kautschuk mit Polyethylen erhöhen die Schlagzähigkeit des Polypropylens stärker als reiner EPDM-Kautschuk. Die Schlagzähigkeit der Mischungen wird durch das Herstellungsverfahren, aber nicht vom Typ des eingesetzten Polyethylens beeinflußt.
    Notes: The effect of the content and type of linear polyethylene, of the type of EPDM rubber and of the preparation procedure on the mechanical properties of ternary blends polypropylene/EPDM rubber/polyethylene was investigated. Mixtures of EPDM rubber with polyethylene raise the impact strength of polypropylene more than pure EPDM rubber. The impact strength of the blends is affected by the procedure employed in the preparation, but not by the type of polyethylene used.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 7 (1986), S. 463-471 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The dynamic mechanical behavior of the binary blends high-density polyethylene/EPDM rubber (ethylene-propylene-diene terpolymer) and isotactic polypropylene/EPDM rubber was investigated by means of a free-oscillating torsional pendulum. Comparison of the moduli of the systems studied and predictions drawn from several models show that phase inversion in the polyethylene/EPDM blends takes place at the volume fraction vPE = 0.5, while polypropylene preserves a certain phase continuity also as the minor component (0.5 〉 vPP 〉 0.2) in blends with EPDM. Because of faster shrinkage in the course of cooling, inclusions are exposed to negative hydrostatic pressure, which accounts for a drop in the glass-transition temperature of the rubber. The strength of the relaxation associated with the glass transition of inclusions and tensile impact strength increase proportionately to the rubber content in polypropylene (0 〈 vEPDM 〈 0.4). Dynamic mechanical response spectra of commercial EPDM/polyethylene impact modifiers are compared with the results for model systems.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 9 (1988), S. 119-124 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The theory of coalescence in melts of polymer blends was derived on the basis of the Smoluchowski theory for colloid systems. An approximation for a flux of particles used for solutions of colloids in water was analyzed. It is shown that this approximation cannot be used for polymer blends, and an approximation is suggested that could be justifiably used for them. A system of equations was derived for the time dependence of the number of individual i-mers, using the relation suggested for the diffusion flux of particles. In an approximation of the uniform increase in particle size, equations were found for the time dependence of the number of particles, the average radius of the particle, and the interface area in the volume unit of the blend. The suggested theory predicts measurable coalescence in considerably more viscous systems than mechanically applied relations of the Smoluchowski theory for aqueous colloid solutions.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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