ISSN:
0570-0833
Keywords:
α-Carbonyl azo compounds
;
Azo compounds
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
α-Carbonyl azo compounds such as diesters of azodicarboxylic acids, diacylazo compounds, and esters of arylazocarboxylic acids are highly reactive. They add e.g. to amines, aromatic compounds, olefins, CH acids, Grignard and diazo compounds, aldehydes, ketones, and ketenes. These reactions can be used for the preparation of triazanes, hydrazones, oxa-diazoline, azomethinimine, and diazetidine derivatives, etc. α,α′-Dicarbonyl azo compounds are among the strongest dienophiles known.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196603721
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