ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(SP)-9-Anthryl(l-menthyloxy)phenylphosphine-borane and (SP)-(1-l-menthyloxy)benzo[b]phosphole-borane were synthesized, and their structures were characterized by X-ray crystallographic analysis. The latter compound was reduced by lithium naphthalenide at -78°C with cleavage of the P—O bond, and the subsequent reaction with electrophiles afforded the corresponding tertiary phosphine-boranes possessing good to excellent enantiomeric excesses.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520060204
Permalink