ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
HCO radical at a concentration of about 1014 cm-3 is produced by monochromatic laser photolysis of H2CO with a 0.6 mJ frequency-doubled, flashlamp-pumped dye laser pulse. Intracavity dye laser spectroscopy quantitatively monitors HCO absorbance near 614 nm as a function of delay time between photolysis and probing pulses. Rate constants for HCO + O2 and HCO + NO are found to be 4.0 ± 0.8 × 10-12 and 1.45 ± 0.2 × 10-11 cm3 molecule-1 sec-1.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550100502
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