ISSN:
0009-2940
Schlagwort(e):
Diphosphorus compounds, mixed valence λ4P+λ4P+, PP-bonded
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Preparation and Single-Crystal X-ray Structure Investigations of some N,N′-Dimethylurea-Bridged Diphosphorus Compounds: NMR Studies of a λ4P+ λ4P+ -Diphosphorus CompoundThe synthesis of N,N′-dimethylurea-bridged diphosphorus compounds involving the structural elements λ3Pλ4P+ (3b, 3c, and 7) and λ4P+λ4P+ (4 and 8) is described. The salts 4 and 8 were obtained by methylation of the λ3Pλ4P+ compounds 3c and 7 with MeOSO2CF3. The λ3P atom in 3c and 7 coordinates to tungsten(0) with formation of the ionic pentacarbonyl derivatives 9 and 10. The NMR spectra of the diphosphonium salt 4 were completely analyzed using NOE and 2D shift correlation experiments (13C,1H and 31P,1H). The single crystal X-ray structure determinations of 3b and 9 are reported. 3b found to crystallize as a hemisolvate with dichloromethane. The RR/SS diastereomer is present in the crystal. The PP distance amounts to 219.1 pm. Both phosphorus atoms interact weakly with the chloride ion (293, 312 pm). 9 crystallizes as a hemisolvate with toluene, the RS/SR diastereomer being present. A PP distance of 224.7 pm and weak interactions between the phosphorus atoms and an oxygen atom of the anion (305, 308 pm) are found.
Zusätzliches Material:
5 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19901230108
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