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Digitale Medien

A Class of Trinuclear Clusters with Carbonyl Bridging (1980)

Pinhas, Allan R. ; Albright, Thomas A. ; Hofmann, Peter ; [weitere]

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 63 (1980), S. 29-49

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ISSN: 0018-019X

Schlagwort(e): Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The impetus for this work was the structure of a trinuclear complex with two carbonyl groups showing incipient triple bridging - Cp2Rh3(CO)4-. Its structure, barrier to rotation of one Rh(CO)2- piece vs. the rest of the molecule, and the nature of the bridging carbonyl interaction are analyzed. Isolobal analogies form an interesting connection between this complex and a bridged isomer of the recently synthesized carbene complexes, Cp2Rh2(CO)2CR2, one isomer of Cp2Rh3(CO)3, and hypothetical carbyne complexes Cp2Rh2(CO)2CH+,-. A general bonding model for Cp2Rh2(μ-CO)2X complexes is constructed. The model, rich in geometrical detail, allows minima for the bridging carbonyl groups bending toward and away from the bonded ligand X.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/hlca.19800630105

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