ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
13C NMR Spectra for a series of 11 substituted cyclobutanes derived from photodimerization of benzocycloalkenes were recorded. Comparison of the carbon chemical shifts for the head-to-head and head-to-tail cis-syn-cis and cis-anti-cis isomers reveals shielding trends which should facilitate structural and stereochemical assignments for related compounds. The head-to-head isomers show a larger separation of cyclobutane carbon resonances than the head-to-tail isomers. The cis-syn-cis isomers relative to the cis-anti-cis isomers exhibit distinctive upfield shifts of all carbon resonances, except those of aromatic carbons ortho to alkyl-substituted aromatic carbons.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270121002
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