ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The palladium catalysed reaction of butadiene with aldehydes yields 2-substituted 3,6-divinyl-tetrahydropyrans.1-4 The reaction has been extended to isoprene and myrcene. With formaldehyde only 2,5-substituted pyrans have been isolated. The isomeric tetrahydropyrans obtained were fully characterised by 1H NMR, and representative 300 MHz spectra are given. Attempts to react aldehydes with 2-methoxybutadiene were unsuccessful.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270051208
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