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Mechanismus der Mutarotation von 5,6-Dibromcholestan (1952)

Grob, C. A. ; Winstein, S.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 35 (1952), S. 782-802

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The mutarotation of 5 α, 6 β-dibromocholestane in a series of solvents and that of cholesterol dibromide in chloroform has been studied polarimetrically. The rate of mutarotation is quite insensitive to the addition of hydrogen bromide, benzoyl peroxide or catechol, the kineties being well formulated by reversible first order reactions.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19520350315

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