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Chromium(VI)-Catalyzed Oxidations by Hydrogen Peroxide: Influence of the Presence of Water and Base (1998)

Bouquillon, Sandrine ; Aït-Mohand, Samia ; Muzart, Jacques

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 2599-2602

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ISSN: 1434-193X

Keywords: Alcohols ; Chromium ; Oxidations ; Sodium percarbonate ; Peroxides ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The chromium(VI)-catalyzed oxidation of 1-indanol into 1-indanone has been carried out with sodium percarbonate (SPC), urea-hydrogen peroxide adduct (UHP), or aqueous hydrogen peroxide. It has been established that the superiority of SPC over UHP and aqueous H2O2 is due both to its nonhydrated structure and its basic properties. This classifies SPC as a “dry basic carrier of H2O2”.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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