ISSN:
1572-8862
Keywords:
Cluster chemistry
;
scorpion geometry
;
gold acetylide
;
ruthenium
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The reaction between Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 and Au(C2Ph)(PPh3) afforded AuRu5(μ5-C2PPh2)(μ-C2Ph)(μ-PPh2)(CO)13 (PPh3), in which the Ru5 cluster has a scorpion geometry; the Au(PPh3) group bridges one of the Ru-Ru bonds of the Ru3 triangle, while the C2Ph group bridges one of the tail Ru-Ru vectors.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00702884
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