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  • 1
    ISSN: 1435-1528
    Keywords: Key words Mixed cationic surfactants ; Turbulent drag reduction ; Rheology ; Apparent extensional viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract Experimental studies of the effects of mixtures of cationic surfactants on their drag reduction and rheological behaviors are reported. Cationic alkyl trimethyl quaternary ammonium surfactants with alkyl chain lengths of C12 and C22 were mixed at different molar ratios (total surfactant concentrations were kept at 5 mM with 12.5 mM sodium salicylate (NaSal) as counterion). Drag reduction tests showed that by adding 10% (mol) of C12, the effective drag reduction range expanded to 4–120 °C, compared with 80–130 °C with only the C22 surfactant. Thus mixing cationic surfactants with different alkyl chain lengths is an effective way of tuning the drag reduction temperature range. Cryo-TEM micrographs revealed thread-like micellar networks for surfactant solutions in the drag reducing temperature range, while vesicles were the dominant microstructures at non-drag reducing temperatures. High extensional viscosity was the main rheological feature for all solutions except 50% C12 (mol) solution, which also does not show strong viscoelasticity. It is not clear why this low extensional viscosity solution with relatively weak viscoelasticity is a good drag reducer.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 6 (1986), S. 819-839 
    ISSN: 0271-2091
    Keywords: Lubricated Flow ; Extensional Flow ; Compression Moulding ; Two-Liquid Interface Flow ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A thin film of low-viscosity lubricating liquid between a solid wall and a viscous material reduces shear stress on the latter and tends to make it flow as though it were slipping along the wall. The result when the lubricated material is being squeezed out of the gap between approaching parallel plates is flow more nearly irrotational, or extensional, the more effective the lubricating film on the plates. Two Newtonian analyses of this flow situation are reported. One is an approximate, asymptotic analytical solution for Newtonian lubricating flow in the films and combined mixed flow, shear and extension, in the viscous layer. The second is a full two-dimensional axisymmetric solution of the momentum and continuity equations along with the kinematic condition which governs the motion of the interface. Both analyses indicate that there are two limiting flow regimes, depending on the ratio of the thickness of each of the two phases to radius and on the viscosity ratio of the two liquids. In one limit the flow is parallel squeezing and the lubricant layer slowly thins and persists a long time. In the other the lubricant is expelled preferentially. Implications of the results are discussed for rheological characterization of viscoelastic liquids and for prediction of lubricated or autolubricated flows in processing situations.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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