Library

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Conductance and ion association in dimethylsulfite (1986)
    Springer
    Journal of solution chemistry 15 (1986), S. 663-673 
    Details
    ISSN: 1572-8927
    Keywords: Conductivities ; Ion association ; 1∶1 electrolytes ; acetone ; dimethylsulfite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electrolytic conductances of LiClO4, LiAsF6, NaClO4 and the n-butylammonium salts Bu4NCl, Bu4NClO4, and Bu4NBPh4 (tetraphenylborate) have been determined in dimethylsufite at 25°C. Ion association constants calculated from these data are interpreted in terms of solvent-separated ion pairs (for LiClO4, LiAsF6, and NaClO4), and contact ion pairs (for the n-butyl-ammonium salts). Comparisons are made for analogous electrolytes in acetone, and in which all salts form contact ion pairs.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00644598
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Conductance of 1:1 electrolytes in methyl formate (1987)
    Springer
    Journal of solution chemistry 16 (1987), S. 225-235 
    Details
    ISSN: 1572-8927
    Keywords: Conductivities ; 1:1 electrolytes ; methyl formate ; ion pairs ; triple ions ; ion solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electrolytic conductivities of LiClO4, LiAlCl4, LiAsF6, NaClO4, NaBPh4, and Bu4NClO4 have been measured in methyl formate at 25°C. Evidence is presented for strong association between the perchlorate ion and the formyl proton of the solvent. Ion association and triple ion formation constants suggest that LiClO4, LiAlCl4, and NaClO4 form solvent separate ion pairs and triple ions. NaBPh4 forms contact ion pairs and triple ions, and the remaining salts appear to form both types of ion pairs and triple ions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00646988
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...