ISSN:
0749-1581
Keywords:
NMR
;
rα structure of benzene and chlorobenzene
;
Correction of deformation
;
Bond contribution to orientation
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Solvent effects on the structures of benzene and chlorobenzene were studied by NMR of partially oriented molecules in six liquid crystals. Allowing for the correlation between vibration and rotation, a unique solvent-independent rα structure could be determined for both molecules. The contributions of equivalent bonds to the orientation energy of the two molecules were found to differ slightly.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260270407
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