Bibliothek

X
feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • Digitale Medien  (2)
  • Cp  (2)
  • 1
    Digitale Medien
    Digitale Medien
    Advantages to Conversion of Lattice Heat Capacity to Cv in the Resolution of Excess Properties The Ln2S3's as an example (1998)
    Springer
    Journal of thermal analysis and calorimetry 52 (1998), S. 1055-1062 
    Details
    ISSN: 1572-8943
    Schlagwort(e): Cp ; Cv ; entropies ; Ln2S3 ; phonon dispersion
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract This paper represents a fitting (modeling) of the temperature dependence of the Komada-Westrum characteristic temperature for those γ-, δ- and ε-phase lanthanide sesquisulfides for which the total heat capacities, including internal degrees of freedom (e.g., Schottky and magnetic contributions), were connected to the residue of only lattice vibrations yielding lattice heat-capacity contributions. These characteristic temperatures (θKW) at 298.15 K are seen to behave smoothly (nearly linearly) as a function of (cationic) atomic number within the region of stability of each phase as does the density. The trends between the phases also show some consistency but not predictability of one from the other.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1010153110658
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 2
    Digitale Medien
    Digitale Medien
    Modeling Sub- and Super-ambient Heat Capacities of the Group Iva Compounds Despite the Lanthanide Contraction (1999)
    Springer
    Journal of thermal analysis and calorimetry 57 (1999), S. 659-667 
    Details
    ISSN: 1572-8943
    Schlagwort(e): Cp ; Cv ; entropies ; group IVA element compounds ; Hf ; Zr
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract This paper is concerned with the estimation of heat capacities in the IVA 3d-transition element compounds using especially Zr and Hf compounds as examples. Most prediction schemes routinely tacitly assume that volumes and masses trend ‘in parallel’. However, the lanthanide contraction here ensures for ZrX/HfX systems — and generally elsewhere — that this is not so in this portion of the periodic table. Available methods such as Latimer's, Volumetric Priority, Komada-Westrum, Grimvall's, and Sommers' are compared on IVA elements and compounds. Only the Sommers approach has volumetric input. It provides the best prediction.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1010111908035
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...