ISSN:
1572-9001
Schlagwort(e):
Enaminonitrile
;
rotational barrier
;
push-pull olefin
;
total line-shape analysis
;
DNMR6
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract Rotational isomerism in enaminonitriles was studied using dynamic NMR spectroscopy and molecular modeling. It was found that the barrier to rotation about Cvinyl-NH bond was higher for enaminonitriles derived from aliphatic amines than that of enaminonitriles derived from aromatic amines. It was also found that the rotational isomerism about the Car-Cvinyl bond also exists in enaminonitriles.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF02272344
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