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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Biology and fertility of soils 5 (1988), S. 276-281 
    ISSN: 1432-0789
    Schlagwort(e): Metolachlor ; Biodegradation ; Soil perfusion ; Microbial metabolites ; Dechlorination ; Actinomyces spp.
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Degradation of the herbicide metachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] was studied in a soil perfusion system. After 28 days of perfusion, the 14CO2 evolved from a Virginia soil (soil A), which had been previously treated with metolachlor (Dual) for 5 years, accounted for 18.4% of the added 14C-metolachlor, while only 3.5% of the 14C was liberated as 14CO2 from a soil of the same field which had no history of Dual treatment (soil B). No 14CO2 was liberated from γ-irradiated soil A. After incubation, metolachlor constituted almost all the extractable 14C in sterile soil A, while about 20% of the added 14C extracted from non-sterile soil A consisted of products of metolachlor; 14.8% was identified as dechlorinated metolachlor. No mineralization occurred in actinomycete-inoculated sterile soil A, but 30% of the added 14C was recovered in the form of transformation products of metolachlor. Our results demonstrate clearly that microbial activity is responsible for the mineralization of metolachlor, and that degradation is enhanced in herbicide-acclimated soils.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    ISSN: 1432-072X
    Schlagwort(e): Laccase ; Syringic acid ; Vanillic acid ; 2-methoxy-1,4-benzoquinone ; Rhizoctonia praticola ; Trametes versicolor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Laccases (benzenediol: oxygen oxidoreductases, EC 1.10.3.2) from Rhizoctonia praticola and Trametes versicolor formed different products from syringic and vanillic acids at different pH values, but both enzymes generated the same chemicals at a particular pH. The products were separated by thin-layer and high-performance liquid chromatography. Four compounds were determined from syringic acid (m/z 168, 334, 350 and 486) at pH 6.9, but only two of these (m/z 168 and 334) were found at pH 3.5. In the case of vanillic acid two isomeric dimers (m/z 304) and 2-methoxy-1,4-benzoquinone (m/z 138) were identified. The dimers were formed at both pH values (pH 3.5 and 6.9), but 2-methoxy-1,4-benzoquinone appeared only at pH 3.5.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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