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Difluoro- and Dichlorodioxasilirane (1990)

Patyk, Andreas ; Sander, Wolfram ; Gauss, Jürgen ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 89-90

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ISSN: 0009-2940

Keywords: Dioxasilirane/Silylene oxidation/Matrix isolation ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reaction of difluorosilylene and dichlorosilylene with molecular oxygen in Ar matrices has been investigated. Under the reaction conditions the silylenes proved to be of low thermal reactivity, and irradiation in the UV/VIS was necessary to produce difluorodioxasilirane and dichlorodioxasilirane, respectively. The IR spectra have been assigned by isotopic labelling and by comparison with ab initio calculations.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19901230119

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