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  • 1
    Electronic Resource
    Electronic Resource
    The Versatile Trimethylenemethane Diyl; Diyl Trapping Reactions - Retrospective and New Modes of Reactivity (1998)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 1-12 
    Details
    ISSN: 1434-193X
    Keywords: TMM ; Diyl trapping reaction ; DNA cleavage ; Atom transfer ; Diradical-induced vinylcyclopropane fragmentation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The diyl trapping reaction has been applied as the key step in the assembly of a variety of ring systems. An overview of the various modes of reactivity of the trimethylenemethane (TMM) diyl is presented, detailing both the mechanistic features affecting selectivity as well as several applications directed towards the synthesis of a variety of natural products. Also highlighted are two new areas of focus, atom transfer and diyl-induced vinylcyclopropane ring opening.
    Type of Medium: Electronic Resource
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