ISSN:
1434-4475
Keywords:
Disiloxanes
;
Organylaminosilanes
;
Alkanolysis
;
Mass spectra interpretation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Reaction of hexachlorodisiloxane with primary and secondary amines leads — in dependence of stoichiometry — to numerous partially and totally organylamino substituted disiloxanes. Partially aminosubstituted chlorodisiloxanes are very sensitive to moisture and can be converted into disiloxanes with different organylamino groups. Exhaustive alkanolysis substitutes amino as well as chloro groups giving hexaalkoxydisiloxanes, but partial alkanolysis may substitute amino in preference to chloro groups. Mass spectra can be interpreted by abstraction ofRR′N·,RR′N+,RR′NH and (RR′N minus H) units. Most of the compounds are colourless liquids but hexakis(piperidino)-disiloxane melts at 270 °C.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00808949
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