Library

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Gas chromatographic behaviour of isomeric tricyclo[10.4.0.04,9]hexadecanes (1992)
    Springer
    Chromatographia 34 (1992), S. 253-258 
    Details
    ISSN: 1612-1112
    Keywords: Multidimensional gas chromatography ; Isomer separation ; Enantiomer separation ; Permethylated β-cyclodextrin chiral phase ; Isomeric tricyclo[10.4.0.04,9]hexadecanes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Using achiral stationary phases of different polarity in capillary gas chromatography it is demonstrated that the hydration of 1,2–5,6-dibenzocycloocta-1,5-diene yields five isomers of the tricyclo[10.4.0.04,9]hexadecanes. With highly polar stationary phases all isomers of the tricyclic hexadecanes and the semihydrated products in the mixture were also separated from each other. The chiral isomers were separated on cyclodextrin stationary phase. Moreover, with columns of achiral and chiral phases coupled in series, in a double oven gas chromatograph, it was possible to estimate the configuration of the isomers. The separation of diastereomers on chiral stationary phases is a useful means for structural assignment of isomeric compounds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02268354
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Two-quasiparticle bands in126Ba (1987)
    Springer
    The European physical journal 327 (1987), S. 251-265 
    Details
    ISSN: 1434-601X
    Keywords: 21.10−k ; 21.10.Hw ; 27.60.+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract High spin states of126Ba have been populated via the116Sn (13C, 3n) reaction and were investigated by inbeam gamma-ray spectroscopy. Partially NaJ (Tl)-BGO anti-compton shields were used. Two positive parity band crossings were established. The yrast band was observed up to a tentative 18+ level. The gamma-bands and two band structures of negative parity were found. In addition a tentative 3− state has been seen. Two-quasiparticle Routhians are constructed from the one-quasiparticle Routhians of the bands in the odd neighbouring isotopes and isotones and are compared to the ones observed in126Ba. This leads to ah 11/2 g 7/2-neutron structure of the strongly coupled negative parity bands and a two-quasiproton structure of the decoupled bands of negative parity. The branching and mixing ratios for the neutron bands are analyzed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01284448
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Enantiomer separation of side-chain fluorinated alkylbenzenes by capillary gas chromatography on cyclodextrin phases (1994)
    Springer
    Chromatographia 39 (1994), S. 192-199 
    Details
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Enantiomer separation ; Permethylated cyclodextrin stationary phases ; Side-chain fluorinated alkylbenzenes ; Thermodynamic data
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The separation of racemic side-chain fluorinated alkylbenzenes and bromofluorinated analogues by capillary gas chromatography using permethylated α, β and γ-cyclodextrins dissolved in polysiloxanes of different polarity as stationary phases is described. The influence of the achiral polysiloxane matrices on the separation of enantiomers is discussed in the light of the results obtained with the different phases. For a part of the tested compounds thermodynamic data are determined which describe the interaction of enantiomers with the stationary phase. The mechanism of separation is discussed on this basis and by comparison with data for structurally similar compounds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02274500
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...