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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 57 (1989), S. 1069-1098 
    ISSN: 1572-9613
    Schlagwort(e): Block copolymers ; generating function ; Polya's theorem ; gelation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We determine the statistical properties of block copolymer complexes in solution. These complexes are assumed to have the topological structure of (i) a tree or of (ii) a line-dressed tree. In case the structure is that of a tree, the system is shown to undergo a gelation transition at sufficiently high polymer concentration. However, if the structure is that of a line-dressed tree, this transition is absent. Hence, we show the assumption about the topological structure to be relevant for the statistical properties of the system. We determine the average size of the complexes and calculate the viscosity of the system under the assumption that the complexes geometrically can be treated as porous spheres.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 57 (1989), S. 1099-1122 
    ISSN: 1572-9613
    Schlagwort(e): Block copolymers ; generating function method ; Polya's theorem ; gelation ; nonnested structures
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We determine the statistical properties of block copolymers in solution. These complexes are assumed to have the topological structure of connected graphs with “nonnested” loops and cycles. The generating function method is used to determine the number of topologically different complexes containing a given number of block copolymers. It is shown that at sufficiently high concentration the system undergoes a transition to a gel phase. Furthermore, the average number of polymers per complex is calculated. Finally, the relative increase in viscosity is found under the assumption that the complexes can be treated as porous spheres.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Flow, turbulence and combustion 59 (1997), S. 315-329 
    ISSN: 1573-1987
    Schlagwort(e): incompressible attachment-line flow ; hydrodynamic stability ; Jacobi–Davidson method ; sparse quadratic eigenvalue systems
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract We consider the linear stability of incompressible attachment-line flow within the spatial framework. No similarity or symmetry assumptions for the instability modes are introduced and the full two-dimensional representation of the modes is used. The perturbation equations are discretized on a two-dimensional staggered grid. A high order finite difference scheme has been developed which gives rise to a large, sparse, quadratic, eigenvalue problem for the instability modes. The benefits of the Jacobi–Davidson method for the solution of this eigenvalue system are demonstrated and the approach is validated in some detail. Spatial stability results are presented subsequently. In particular, instability predictions at very high Reynolds numbers are obtained which show almost equally strong instabilities for symmetric and antisymmetric modes in this regime.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Communications in Numerical Methods in Engineering 10 (1994), S. 785-790 
    ISSN: 1069-8299
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Second- and fourth-order-accurate spatial discretization methods give rise to discretization errors which are large than the corresponding subgrid terms in large eddy simulation of compressible shear layers in 2D, if the ratio between the filter width and the grid spacing is close to one. Even if an exact representation for the subgrid-scale contributions is assumed, large eddy simulation is accurate only if this ratio is sufficiently larger than one. In that regime fourth-order methods are more accurate than second-order methods. An analysis of the data obtained from two-dimensional direct numerical simulations of compressible shear layers substantiates these assertions.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 22 (1996), S. 297-311 
    ISSN: 0271-2091
    Schlagwort(e): large-eddy simulation ; numerical schemes ; mixing layer ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A posteriori tests of large-eddy simulations for the temporal mixing layer are performed using a variety of numerical methods in conjunction with the dynamic mixed subgrid model for the turbulent stress tensor. The results of the large-eddy simulations are compared with filtered direct numerical simulation (DNS) results. Five numerical methods are considered. The cell vertex scheme (A) is a weighted second-order central difference. The transverse weighting is shown to be necessary, since the standard second-order central difference (A′) gives rise to instabilities. By analogy, a new weighted fourth-order central difference (B) is constructed in order to overcome the instability in simulations with the standard fourth-order central method (B′). Furthermore, a spectral scheme (C) is tested. Simulations using these schemes have been performed for the case where the filter width equals the grid size (I) and the case where the filter width equals twice the grid size (II). The filtered DNS results are best approximated in case II for each of the numerical methods A, B and C. The deviations from the filtered DNS data are decomposed into modelling error effects and discretization error effects. In case I the absolute modelling error effects are smaller than in case II owing to the smaller filter width, whereas the discretization error effects are larger, since the flow field contains more small-scale contributions. In case I scheme A is preferred over scheme B, whereas in case II the situation is the reverse. In both cases the spectral scheme C provides the most accurate results but at the expense of a considerably increased computational cost. For the prediction of some quantities the discretization errors are observed to eliminate the modelling errors to some extent and give rise to reduced total errors.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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