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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 42-49 
    ISSN: 1572-8943
    Keywords: evolved gas analysis ; FTIR ; MS ; pyrolysis-GC-MS ; thermogravimetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal decomposition of sodium ethyl xanthate (SEX) was used to compare the techniques of pyrolysis-gas chromatography-mass spectrometry (py-GC-MS), thermogravimetry-Fourier transform infrared spectroscopy (TG-FTIR), and TG-MS. In the py-GC-MS analysis, SEX was pyrolysed at 400°C in an inert atmosphere. Major gases evolved were carbon disulfide, diethyl sulfide, ethanol, and carbonyl sulfide. The TG of SEX exhibited a sharp mass loss at 201°C (42.3%) and a gradual mass loss at 217-325°C (20.8 %). The MS spectra of the evolved gases were complex due to overlapping of molecular, isotope, and fragment ion signals. Using the MS in selected ion monitoring mode, the major gases evolved were found to be carbon disulfide and carbonyl sulfide. The FTIR spectra of the evolved gases displayed vibrational frequencies due to alkanes, carbonyls, carbonyl sulfide, and carbon disulfide. From the analyses it was concluded that py-GC-MS provided unambiguous gas identification. Interpretation of the MS results was reliant on the py-GC-MS results, and the FTIR data was limited to identifying gases with very characteristic vibration frequencies.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 93 (1997), S. 321-330 
    ISSN: 1573-2932
    Keywords: moss ; cadmium ; chromium ; zinc ; bioindicators ; contamination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a series of laboratory experiments employing radiotracer methodology, the uptake of Cd, Cr, and Zn bySphagnum papillosum Lindle moss from solutions of deionized water and bog water was investigated. Bioaccumulation of the metals was a passive process, since living and dead moss accumulated metal equally. No significant differences were found in metal uptake rates from single metal solutions and mixed metal solutions, suggesting insignificant competition between the metals occurred at the low concentration range used (10−10 to 10−7 M). Metal uptake conformed with Freundlich adsorption isotherms. Concentration factors of metals inSphagnum papillosum in bog water (103 for Cd and Zn, 102 for Cr) were lower than in deionized water (104 for Cd and Zn, 103 for Cr), possibly due to metal complexation by dissolved organic matter, competition by other major cations present in the bog water (Na+, K+, Mg2+, Ca2+) or complexation by chlorides in the bog water. While earlier studies have demonstrated the potential of using sphagnum mosses for monitoring environmental metal contamination, these experiments are the first to assess metal uptake in moss using low, environmentally realistic metal concentrations. The results confirm that mosses would be very effective bioindicators of environmental metal concentrations because the concentration of metal in the moss rapidly and directly reflects the metal concentrations in the ambient water.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 93 (1997), S. 321-330 
    ISSN: 1573-2932
    Keywords: moss ; cadmium ; chromium ; zinc ; bioindicators ; contamination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a series of laboratory experiments employing radiotracer methodology, the uptake of Cd,Cr, and Zn by Sphagnum papillosum Lindle moss from solutions of deionized water and bogwater was investigated. Bioaccumulation of the metals was a passive process, since living anddead moss accumulated metal equally. No significant differences were found in metal uptake ratesfrom single metal solutions and mixed metal solutions, suggesting insignificant competitionbetween the metals occurred at the low concentration range used (10-10 to 10-7 M). Metaluptake conformed with Freundlich adsorption isotherms. Concentration factors of metals inSphagnum papillosum in bog water (103 for Cd and Zn, 102 for Cr) were lower than in deionizedwater (104 for Cd and Zn, 103 for Cr), possibly due to metal complexation by dissolved organicmatter, competition by other major cations present in the bog water (Na+, K+, Mg2+, Ca2+) orcomplexation by chlorides in the bog water. While earlier studies have demonstrated the potentialof using sphagnum mosses for monitoring environmental metal contamination, these experimentsare the first to assess metal uptake in moss using low, environmentally realistic metalconcentrations. The results confirm that mosses would be very effective bioindicators ofenvironmental metal concentrations because the concentration of metal in the moss rapidly anddirectly reflects the metal concentrations in the ambient water.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
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