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  • 1
    ISSN: 1432-0649
    Keywords: 33.20E ; 42.55H
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract High-resolution Fourier transform spectroscopy has been applied to confirm previously proposed assignments for nine far infrared (FIR) laser lines from the CH3-deformation state of CH3OH and one line from the CH3-rocking state. Accurate frequencies are deduced for the observed and other predicted FIR laser transitions. FIR torsional branch frequencies in the ground state which were used in the confirmation are presented. Comments are also made on the OH-bending mode of CH3OH.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of infrared and millimeter waves 14 (1993), S. 1727-1753 
    ISSN: 1572-9559
    Keywords: Far-infrared (FIR) ; spectra ; methanol ; CD3OH ; torsion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The Fourier transform far-infrared (FTFIR) spectrum of CD3OH has been obtained from 40–220 cm−1 at a resolution of 0.002 cm−1, and partially analyzed. Numerousb-type branches have been assigned in the spectrum, ranging over torsional states fromn=0 to 3. The branches have been fitted toJ(J+1) power-series energy expansions in order to obtainJ-independent branch origins. These in turn have been fitted to the torsion-rotation Hamiltonian, and improved molecular constants have been obtained for the ground vibrational state.
    Type of Medium: Electronic Resource
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