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Far infrared spectrum of CD3OH methanol from 40–220 CM−1 (1993)

Mollabashi, Mahmoud ; Lees, R. M. ; Johns, J. W. C.

Springer

International journal of infrared and millimeter waves 14 (1993), S. 1727-1753

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ISSN: 1572-9559

Keywords: Far-infrared (FIR) ; spectra ; methanol ; CD3OH ; torsion

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The Fourier transform far-infrared (FTFIR) spectrum of CD3OH has been obtained from 40–220 cm−1 at a resolution of 0.002 cm−1, and partially analyzed. Numerousb-type branches have been assigned in the spectrum, ranging over torsional states fromn=0 to 3. The branches have been fitted toJ(J+1) power-series energy expansions in order to obtainJ-independent branch origins. These in turn have been fitted to the torsion-rotation Hamiltonian, and improved molecular constants have been obtained for the ground vibrational state.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02101329

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