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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 10 (1981), S. 757-774 
    ISSN: 1572-8927
    Keywords: Cu(II)/Cu(I) couple ; Cu(I)/Cu(0) couple ; acetonitrile-water mixtures ; Fe(III) ; 2-hydroxycyanoethane ; electrochemistry ; voltammetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electrochemical characteristics of the Cu (II)/Cu (I) and the Cu (I)/Cu (0) couples at platinum, carbon, mercury and copper have been studied in acetonitrile-water (AN-H2O) mixtures. All the electrode processes are moderately fast with mercury the fastest but slower on platinum and carbon paste in that order. A slow chemical step precedes oxidation of Cu (I) to Cu (II) on allectrodes in solutions of high AN content. The slow step may be partial removal of AN from the solvated Cu (I) ion prior to electron transfer. Electrode processes are faster in chloride ions than in sulfate ion solutions. Reduction of Cu (I) in AN−H2O is quite slow on glassy carbon. Adsorption of AN on platinum and carbon influences the processes. Diffusion coefficients in sulfate solutions are in the order, Cu (I) (AN−H2O)〉Cu (II)(AN−H2O)〉Fe (III)(H2O) and 2-hydroxy-cyanoethane (2-HCE) strongly decreases the mobility of Cu (I) when added to H2O. The relevance of the measurements to hydrometallurgical processes is considered. CuSO4 in 30% v/v AN−H2O is a ‘faster’ oxidant than the common oxidant Fe2(SO4)3 in H2O because of the greater mobility and faster electron acceptance from a corroding surface of Cu (II). Only in solutions of very high nitrile content is the reduction potential of CuSO4 as high as that of Fe2(SO4)3 in H2O.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5036
    Keywords: Available N and P ; Azolla ; Blue-green algae ; Mineralization ; Organic manures ; Rice soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Pot incubation study with fresh Azolla (Azolla pinnata-India and Vietnam isolates,A. mexicana andA. filiculoides), blue-green algaAulosira sp., green manureSesbania cannabina, Azolla compost, farm yard manure and ammonium sulphate was conducted under flooded condition at CRRI, Cuttack keeping an equivalent amount of 25 ppm N through all the amendments where changes in availability of N and P, C∶N ratio and pH were recorded. Application of chemical N-fertilizer recorded a release of about 87% NH4 +−N at 10th day of flooding which gradually decreased and reached the minimum of 6% at 50 days. The C∶N ratio of the organic manures ranged between 9–10 favouring release of NH4 +−N and among theAzolla speciesA. pinnata isolates released NH4 +−N more efficiently thanA. filiculoides andA. mexicana. A. pinnata Indian isolate released maximum of 88% NH4 +−N, whereas Vietnam isolate recorded 77% at 40 days of flooding; green manure on the other hand, reached a maximum of 50% release at 50 days. The blue-green alga recorded a gradual increase and attained the maximum release of 38% at 40 days of flooding. Farmyard manure recorded a highest NH4 +−N release of 69% at 20 days of flooding and gradual decrease thereafter, whereas Azolla compost released 41% at 40 days of flooding. Soil amended with fresh organic matter achieved reduction upto a pH of 7.2 after 50 days of flooding, whereas the pH in Azolla compost and farmyard manure amendment was 〈7. The P availability increased from 20th day onwards and reached the highest values of 26 and 18 ppm in the fresh organic matter and compost amended soil respectively after 40–50 days of flooding. The cumulative release of available P was found superior in fresh Azolla incorporation.
    Type of Medium: Electronic Resource
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