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Chromatographic parameters derived for the non-linear response of a flame photometric detector (1981)

Marriott, P. J. ; Cardwell, T. J.

Springer

Chromatographia 14 (1981), S. 279-284

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Details

ISSN: 1612-1112

Schlagwort(e): Flame photometric detector ; Sulphur mode ; Non-linear detection ; Response factor ; Peak widths

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Summary A mathematical derivation of efficiency and resolution equations for use in conjunction with flame photometric detection of sulphur compounds is presented. These equations are similar to those for linear detection apart from the incorporation of the exponential response factor, n, in the denominator of the respective expressions for non-linear detection. The latter equations reduce to those usually recognised for linear detection if the value n=1 is substituted. Equating the column efficiency equations for linear and non-linear detection permits direct determination of the value of n.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02259266

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