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  • 1
    Electronic Resource
    Electronic Resource
    Synthese von nichtsymmetrisch substituierten Perylen-Fluoreszenzfarbstoffen (1991)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 529-535 
    Details
    ISSN: 0009-2940
    Keywords: Perylene dyes ; Hydrocarbons polycyclic ; Fluorescent dyes ; Fluorescent labelling ; Fluorescent tracer ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Nonsymmetrically Substituted Perylene Fluorescent DyesA general method for the preparation of perylene-3,4:9,10-tetracarboxdiimides 1 with two different substituents at the nitrogen atoms is described: The easily prepared symmetrical tetracarboxdiimides 1 (R1=R2) are transformed into carboxdiimide anhydrides 2 and condensed with primary amines to the corresponding tetracarboxdiimides 1 (R1 ≢ R2). Applications as fluorescent tracers in biochemistry and polymer chemistry are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19911240319
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Synthesis of perylene-3,4-dicarboximides  -  Novel highly photostable fluorescent dyesDedicated to Prof. Dr. Christoph Rüchardt on the occasion of his 65th birthday. (1995)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1995 (1995), S. 1229-1244 
    Details
    ISSN: 0947-3440
    Keywords: Fluorescent dyes ; Pigments ; Perylenes ; Carboximides ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Perylene-3,4-dicarboximides 2 are obtained by a decarboxylizing condensation of moderately sterically hindered primary amines with perylene-3,4,9,10-tetracarboxylic 3,4:9,10-bisanhydride (3) in the presence of water. Perylene-3,4-dicarboxylic anhydride (4) is prepared by hydrolysis of the imides with KOH in tert-butyl alcohol. The anhydride may be condensed with any primary amine to the corresponding imide. The imides are highly fluorescent and very photostable dyes.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.1995199507164
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Balanced Decarboxylation of Aromatic Polyacids - A One-Step Synthesis of Perylene-3,4-dicarboxylic Anhydride (1997)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 467-468 
    Details
    ISSN: 0947-3440
    Keywords: Decarboxylation ; Carboxylic acids ; Fluorescence spectroscopy ; Perylenes ; Heterocycles ; Dyes ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Perylene-3,4-dicarboxylic anhydride (3) is prepared from technical grade perylene-3,4:9,10-tetracarboxylic anhydride (1) in 25% yield by a partial decarboxylation reaction using noncondensing amines. Perylene-3-carboxylic acid (4) and perylene-3,4-dicarboxylic imide (5) are prepared in the same way in yields of 24% and 76%, respectively, by a variation of the reaction conditions.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.199719970305
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  • 4
    Electronic Resource
    Electronic Resource
    Chiral Bifluorophoric Perylene Dyes with Unusually High CD Effects - a Simple Model for the Photosynthesis Reaction Center (1997)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 1151-1153 
    Details
    ISSN: 0947-3440
    Keywords: Fluorescent dyes ; Perylenes ; Heterocycles ; Photosynthesis reaction center ; CD effects ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of a bifluorophoric perylene dye (4a) is described, in which the two chromophores are linked by a chiral binaphthyl unit. A strong exciton coupling of the two chromophores, a bathochromically shifted fluorescence and strong CD effects are observed. The structure of 4 is compared to the photosynthesis reaction center.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.199719970615
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    Paper (German National Licenses)
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  • 5
    Electronic Resource
    Electronic Resource
    Cyclophanes as Model Compounds for Permanent, Dynamic Aggregates - Induced Chirality with Strong CD Effects (1998)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 1915-1917 
    Details
    ISSN: 1434-193X
    Keywords: Cyclophanes ; Fluorescent dyes ; Perylenes ; Exciton coupling ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dynamic processes, a bathochromically shifted fluorescence, and strong solvent-induced chirality effects are observed for the [12,12]-perylene-bis(imide)-cyclophane 3, which forms a “fixed supramolecule”.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Novel Fluorescent Dyes by the Extension of the Core of Perylenetetracarboxylic Bisimides (2000)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 365-380 
    Details
    ISSN: 1434-193X
    Keywords: Fluorescent dyes ; Perylenes ; Heterocycles ; NIR dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Core-extended perylenetetracarboxylic bisimides were prepared by Diels-Alder reaction followed by reduction, or by nitration followed by cyclisation. Highly fluorescent dyes were obtained with absorption regions from the visible to the NIR. Applications for solar energy harvesting, and quantum counters were suggested.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 7
    Electronic Resource
    Electronic Resource
    The Synthesis of Perylenebisimide Monocarboxylic Acids (1998)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 847-851 
    Details
    ISSN: 1434-193X
    Keywords: Fluorescent dyes ; Perylenes ; Heterocycles ; Carboxylic acids ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis and properties of perylene-bisimides 4 with one carboxylic acid anchor group are described. The properties of 4 are strongly influenced by the spacer between the carboxylic acid group and the imide moeity. Dyes with aliphatic (4d-4g) and aromatic (4a-4c) spacers have been prepared.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 8
    Electronic Resource
    Electronic Resource
    Pyrrolo- and Thiophenoperylenedicarboximides - Highly Fluorescent Heterocycles (1996)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1996 (1996), S. 1587-1591 
    Details
    ISSN: 0947-3440
    Keywords: Perylenes ; Heterocycles ; Fluorescent dyes ; Fluorescent labelling ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Pyrrolo- and thiophenoperylenedicarboximides 4 and 7 were prepared by reductive cyclization of 1-nitroperylenedicarboximides 3 and 5 with phosphorous acid esters and sulfur, respectively. The imides 4 and 7 are highly fluorescent and are easily monofunctionalized by nucleophilic substitution reactions which makes them useful for fluorescent labeling.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.199619961014
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